Royal Society of Chemistry (RSC)
Organic Chemistry Frontiers
,  том 12 ,  издание 6 ,  страницы 1815-1820

An Unexpected Lewis Acid-Catalyzed Cascade Reaction of Bicyclo[1.1.0]butanes with Triazinanes to Biscyclobutenyl Amines

Тип публикации: Journal Article
Дата публикации: 2025-01-08
Royal Society of Chemistry (RSC)
scimago Q1
wos Q1
БС1
SJR: 1.068
CiteScore: 8.2
Impact factor: 4.7
ISSN: 20524110, 20524129
Краткое описание
An unexpected In(OTf)3-catalyzed cascade reaction of bicyclo[1.1.0]butanes with triazinanes is reported, providing a series of butterfly-shaped biscyclobutenyl amines in good yields. This reaction features simple operation, mild reaction conditions, and broad substrate scope. A rational mechanism involving a key carbocation intermediate is proposed.
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Chen F. et al. An Unexpected Lewis Acid-Catalyzed Cascade Reaction of Bicyclo[1.1.0]butanes with Triazinanes to Biscyclobutenyl Amines // Organic Chemistry Frontiers. 2025. Vol. 12. No. 6. pp. 1815-1820.
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Chen F., Duan Y., Guo Y., Liu Y., Lang M., Peng J., Peng S. An Unexpected Lewis Acid-Catalyzed Cascade Reaction of Bicyclo[1.1.0]butanes with Triazinanes to Biscyclobutenyl Amines // Organic Chemistry Frontiers. 2025. Vol. 12. No. 6. pp. 1815-1820.
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TY - JOUR
DO - 10.1039/d4qo02245a
UR - http://pubs.rsc.org/en/Content/ArticleLanding/2025/QO/D4QO02245A
TI - An Unexpected Lewis Acid-Catalyzed Cascade Reaction of Bicyclo[1.1.0]butanes with Triazinanes to Biscyclobutenyl Amines
T2 - Organic Chemistry Frontiers
AU - Chen, Feng
AU - Duan, Yijun
AU - Guo, Ye
AU - Liu, Yuncheng
AU - Lang, Ming
AU - Peng, Jin-Bao
AU - Peng, Shiyong
PY - 2025
DA - 2025/01/08
PB - Royal Society of Chemistry (RSC)
SP - 1815-1820
IS - 6
VL - 12
SN - 2052-4110
SN - 2052-4129
ER -
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@article{2025_Chen,
author = {Feng Chen and Yijun Duan and Ye Guo and Yuncheng Liu and Ming Lang and Jin-Bao Peng and Shiyong Peng},
title = {An Unexpected Lewis Acid-Catalyzed Cascade Reaction of Bicyclo[1.1.0]butanes with Triazinanes to Biscyclobutenyl Amines},
journal = {Organic Chemistry Frontiers},
year = {2025},
volume = {12},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {http://pubs.rsc.org/en/Content/ArticleLanding/2025/QO/D4QO02245A},
number = {6},
pages = {1815--1820},
doi = {10.1039/d4qo02245a}
}
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Chen, Feng, et al. “An Unexpected Lewis Acid-Catalyzed Cascade Reaction of Bicyclo[1.1.0]butanes with Triazinanes to Biscyclobutenyl Amines.” Organic Chemistry Frontiers, vol. 12, no. 6, Jan. 2025, pp. 1815-1820. http://pubs.rsc.org/en/Content/ArticleLanding/2025/QO/D4QO02245A.