Streamlined synthetic assembly of α-chiral CAAC ligands and catalytic performance of their copper and ruthenium complexes

Adrien Madron Du Vigné ¹

Nicolai Cramer ¹

Laboratory of Asymmetric Catalysis and Synthesis, Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland |

Publication type: Journal Article

Publication date: 2024-07-24

Royal Society of Chemistry (RSC)

Journal: Chemical Science

scimago Q1

SJR: 2.333

CiteScore: 14.4

Impact factor: 7.6

ISSN: 20416520, 20416539

DOI: 10.1039/d4sc04278f

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Abstract

A streamlined strategy to diastereo- and enantiomerically pure α,β-chiral CAAC salts and their corresponding transition metal complexes is reported, displaying high enantioselectivities in benchmark asymmetric transformations.

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Publisher

Royal Society of Chemistry (RSC)

Journal

Chemical Science

scimago Q1

SJR

2.333

CiteScore

14.4

Impact factor

7.6

ISSN

20416520 (Print)

20416539 (Electronic)