Hydrothermal synthesis and crystal structure of two Co phosphonates containing trifunctional phosphonate anions: Co3(O3PCH2NH2CH2PO3)2 and Co3(O3PCH2-NC4H7-CO2)2·5H2O
Тип публикации: Journal Article
Дата публикации: 2003-02-25
SCImago Q2
WOS Q2
БС1
SJR: 0.581
CiteScore: 6
Impact factor: 3.3
ISSN: 14779226, 14779234
Inorganic Chemistry
Краткое описание
Two cobalt phosphonates containing trifunctional phosphonate anions have been synthesised and their structures solved by single crystal diffraction. Co3(O3PCH2NH2CH2PO3)2
(3) was formed as blue crystals. The material has three channel systems in the [001] direction formed by the cross-linking of chains of tetrahedrally co-ordinated Co atoms. Co3(O3PCH2-NC4H7-CO2)2·5H2O (4), which contains anions derived from proline, was formed as purple crystals. (4) is composed of layers that contain holes. The layers stack in the [001] direction such that channels are formed in the same direction, in which the water molecules are located.
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Turner A. et al. Hydrothermal synthesis and crystal structure of two Co phosphonates containing trifunctional phosphonate anions: Co3(O3PCH2NH2CH2PO3)2 and Co3(O3PCH2-NC4H7-CO2)2·5H2O // Dalton Transactions. 2003. Vol. 7. pp. 1314-1319.
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Turner A., Jaffrès P., MacLean E. J., Villemin D., McKee V., Hix G. B. Hydrothermal synthesis and crystal structure of two Co phosphonates containing trifunctional phosphonate anions: Co3(O3PCH2NH2CH2PO3)2 and Co3(O3PCH2-NC4H7-CO2)2·5H2O // Dalton Transactions. 2003. Vol. 7. pp. 1314-1319.
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TY - JOUR
DO - 10.1039/b212266a
UR - https://doi.org/10.1039/b212266a
TI - Hydrothermal synthesis and crystal structure of two Co phosphonates containing trifunctional phosphonate anions: Co3(O3PCH2NH2CH2PO3)2 and Co3(O3PCH2-NC4H7-CO2)2·5H2O
T2 - Dalton Transactions
AU - Turner, Adele
AU - Jaffrès, Paul-Alain
AU - MacLean, Elizabeth J.
AU - Villemin, D.
AU - McKee, Vickie
AU - Hix, Gary B.
PY - 2003
DA - 2003/02/25
PB - Royal Society of Chemistry (RSC)
SP - 1314-1319
IS - 7
SN - 1477-9226
SN - 1477-9234
ER -
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@article{2003_Turner,
author = {Adele Turner and Paul-Alain Jaffrès and Elizabeth J. MacLean and D. Villemin and Vickie McKee and Gary B. Hix},
title = {Hydrothermal synthesis and crystal structure of two Co phosphonates containing trifunctional phosphonate anions: Co3(O3PCH2NH2CH2PO3)2 and Co3(O3PCH2-NC4H7-CO2)2·5H2O},
journal = {Dalton Transactions},
year = {2003},
publisher = {Royal Society of Chemistry (RSC)},
month = {feb},
url = {https://doi.org/10.1039/b212266a},
number = {7},
pages = {1314--1319},
doi = {10.1039/b212266a}
}
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