Resorcin[4]arene-derived mono-, bis- and tetra-imidazolium salts as ligand precursors for Suzuki–Miyaura cross-coupling
Hani El Moll
1
,
David Sémeril
1
,
Dominique Matt
1
,
Loïc Toupet
2
,
Jean Jacques Harrowfield
3
,
Jean-Jacques Harrowfield
3
2
Publication type: Journal Article
Publication date: 2012-01-01
scimago Q2
wos Q2
SJR: 0.600
CiteScore: 5.2
Impact factor: 2.7
ISSN: 14770520, 14770539
PubMed ID:
22086349
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
Eleven resorcinarene cavitands bearing either one, two or four (3-R-1-imidazolylium)-methyl substituents (R = (n)Bu, Ph, Mes, (i)Pr(2)C(6)H(3)) anchored at resorcinolic "ortho" positions have been synthesised from the appropriate bromomethylated precursor. Combining the imidazolium salts with palladium acetate and Cs(2)CO(3) gave active Suzuki-Miyaura cross coupling catalysts. The highest activities were observed with the doubly functionalised cavitands, which all have the imidazolylium groups attached to proximal resorcinol units.
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GOST
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Moll H. E. et al. Resorcin[4]arene-derived mono-, bis- and tetra-imidazolium salts as ligand precursors for Suzuki–Miyaura cross-coupling // Organic and Biomolecular Chemistry. 2012. Vol. 10. No. 2. pp. 372-382.
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Moll H. E., Sémeril D., Matt D., Toupet L., Harrowfield J. J., Harrowfield J. Resorcin[4]arene-derived mono-, bis- and tetra-imidazolium salts as ligand precursors for Suzuki–Miyaura cross-coupling // Organic and Biomolecular Chemistry. 2012. Vol. 10. No. 2. pp. 372-382.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/c1ob06404e
UR - https://doi.org/10.1039/c1ob06404e
TI - Resorcin[4]arene-derived mono-, bis- and tetra-imidazolium salts as ligand precursors for Suzuki–Miyaura cross-coupling
T2 - Organic and Biomolecular Chemistry
AU - Moll, Hani El
AU - Sémeril, David
AU - Matt, Dominique
AU - Toupet, Loïc
AU - Harrowfield, Jean Jacques
AU - Harrowfield, Jean-Jacques
PY - 2012
DA - 2012/01/01
PB - Royal Society of Chemistry (RSC)
SP - 372-382
IS - 2
VL - 10
PMID - 22086349
SN - 1477-0520
SN - 1477-0539
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2012_Moll,
author = {Hani El Moll and David Sémeril and Dominique Matt and Loïc Toupet and Jean Jacques Harrowfield and Jean-Jacques Harrowfield},
title = {Resorcin[4]arene-derived mono-, bis- and tetra-imidazolium salts as ligand precursors for Suzuki–Miyaura cross-coupling},
journal = {Organic and Biomolecular Chemistry},
year = {2012},
volume = {10},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/c1ob06404e},
number = {2},
pages = {372--382},
doi = {10.1039/c1ob06404e}
}
Cite this
MLA
Copy
Moll, Hani El, et al. “Resorcin[4]arene-derived mono-, bis- and tetra-imidazolium salts as ligand precursors for Suzuki–Miyaura cross-coupling.” Organic and Biomolecular Chemistry, vol. 10, no. 2, Jan. 2012, pp. 372-382. https://doi.org/10.1039/c1ob06404e.