Ruthenium-based complexes containing a benzimidazolium tag covalently connected to N-heterocyclic carbene ligands: environmentally friendly catalysts for olefin metathesis transformations
Publication type: Journal Article
Publication date: 2013-01-01
scimago Q2
wos Q1
SJR: 0.653
CiteScore: 6.0
Impact factor: 3.3
ISSN: 14779226, 14779234
PubMed ID:
23360984
Inorganic Chemistry
Abstract
Two ruthenium-based pre-catalysts containing an ionic tag covalently connected to a N-heterocyclic carbene (NHC) ligand are reported. These novel complexes, bearing a polar benzimidazolium group, are air-stable and can be easily prepared from commercially available reagents. The quaternary benzimidazolium tag allows the efficient separation of ruthenium waste from the metathesis product after reaction. Application in several olefin metathesis transformations leads to desired products of high purity, which exhibit ruthenium contamination levels as low as 1 ppm after simple filtration through a pad of silica gel.
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Total citations:
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Citations from 2024:
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(3.7%)
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GOST
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Kluciar M. et al. Ruthenium-based complexes containing a benzimidazolium tag covalently connected to N-heterocyclic carbene ligands: environmentally friendly catalysts for olefin metathesis transformations // Dalton Transactions. 2013. Vol. 42. No. 20. p. 7354.
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Kluciar M., Klučiar M., Grela K., Mauduit M. Ruthenium-based complexes containing a benzimidazolium tag covalently connected to N-heterocyclic carbene ligands: environmentally friendly catalysts for olefin metathesis transformations // Dalton Transactions. 2013. Vol. 42. No. 20. p. 7354.
Cite this
RIS
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TY - JOUR
DO - 10.1039/c2dt32856a
UR - https://doi.org/10.1039/c2dt32856a
TI - Ruthenium-based complexes containing a benzimidazolium tag covalently connected to N-heterocyclic carbene ligands: environmentally friendly catalysts for olefin metathesis transformations
T2 - Dalton Transactions
AU - Kluciar, Marek
AU - Klučiar, Marek
AU - Grela, Karol
AU - Mauduit, Marc
PY - 2013
DA - 2013/01/01
PB - Royal Society of Chemistry (RSC)
SP - 7354
IS - 20
VL - 42
PMID - 23360984
SN - 1477-9226
SN - 1477-9234
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2013_Kluciar,
author = {Marek Kluciar and Marek Klučiar and Karol Grela and Marc Mauduit},
title = {Ruthenium-based complexes containing a benzimidazolium tag covalently connected to N-heterocyclic carbene ligands: environmentally friendly catalysts for olefin metathesis transformations},
journal = {Dalton Transactions},
year = {2013},
volume = {42},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/c2dt32856a},
number = {20},
pages = {7354},
doi = {10.1039/c2dt32856a}
}
Cite this
MLA
Copy
Kluciar, Marek, et al. “Ruthenium-based complexes containing a benzimidazolium tag covalently connected to N-heterocyclic carbene ligands: environmentally friendly catalysts for olefin metathesis transformations.” Dalton Transactions, vol. 42, no. 20, Jan. 2013, p. 7354. https://doi.org/10.1039/c2dt32856a.
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