Royal Society of Chemistry (RSC)
Journal of the Chemical Society Chemical Communications
,  издание 22 ,  страницы 1662-1663

Sensitised (electron-transfer) photochemical reactions of cyclopolysilanes, (R1R2Si)n(n= 3 or 4), in a polar, nucleophilic solvent; electron donating nature of cyclopolysilanes (n= 3–7)

Тип публикации: Journal Article
Дата публикации: 1986-01-01
Royal Society of Chemistry (RSC)
SJR: —
CiteScore: —
Impact factor: —
ISSN: 00224936
Molecular Medicine
Краткое описание
Irradiation (<390 nm) of cyclopolysilanes, (R1R2Si)n(n= 3 or 4), in a mixed solvent (EtOH-MeCN-cyclo-C6H12), with 9,10-dicyanoanthracene as sensitiser, gave the corresponding α-ethoxy-ω-hydropolysilanes resulting from ring-opening addition of ethanol to the polysilanes; a mechanism involving facile electron transfer from the polysilanes is proposed.
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Watanabe H. et al. Sensitised (electron-transfer) photochemical reactions of cyclopolysilanes, (R1R2Si)n(n= 3 or 4), in a polar, nucleophilic solvent; electron donating nature of cyclopolysilanes (n= 3–7) // Journal of the Chemical Society Chemical Communications. 1986. Vol. 22. pp. 1662-1663.
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Watanabe H., Kato M., TABEI E., Kuwabara H., Hirai N., Sato T., NAGAI Y. Sensitised (electron-transfer) photochemical reactions of cyclopolysilanes, (R1R2Si)n(n= 3 or 4), in a polar, nucleophilic solvent; electron donating nature of cyclopolysilanes (n= 3–7) // Journal of the Chemical Society Chemical Communications. 1986. Vol. 22. pp. 1662-1663.
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TY - JOUR
DO - 10.1039/c39860001662
UR - https://doi.org/10.1039/c39860001662
TI - Sensitised (electron-transfer) photochemical reactions of cyclopolysilanes, (R1R2Si)n(n= 3 or 4), in a polar, nucleophilic solvent; electron donating nature of cyclopolysilanes (n= 3–7)
T2 - Journal of the Chemical Society Chemical Communications
AU - Watanabe, Hamao
AU - Kato, Motohiko
AU - TABEI, Eiichi
AU - Kuwabara, Haruyoshi
AU - Hirai, Nobuo
AU - Sato, Takeo
AU - NAGAI, Yoichiro
PY - 1986
DA - 1986/01/01
PB - Royal Society of Chemistry (RSC)
SP - 1662-1663
IS - 22
SN - 0022-4936
ER -
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@article{1986_Watanabe,
author = {Hamao Watanabe and Motohiko Kato and Eiichi TABEI and Haruyoshi Kuwabara and Nobuo Hirai and Takeo Sato and Yoichiro NAGAI},
title = {Sensitised (electron-transfer) photochemical reactions of cyclopolysilanes, (R1R2Si)n(n= 3 or 4), in a polar, nucleophilic solvent; electron donating nature of cyclopolysilanes (n= 3–7)},
journal = {Journal of the Chemical Society Chemical Communications},
year = {1986},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/c39860001662},
number = {22},
pages = {1662--1663},
doi = {10.1039/c39860001662}
}