Ruthenium(ii) carbonyl complexes bearing CCC-pincer bis-(carbene) ligands: synthesis, structures and activities toward recycle transfer hydrogenation reactions
Publication type: Journal Article
Publication date: 2013-06-17
scimago Q2
wos Q1
SJR: 0.653
CiteScore: 6.0
Impact factor: 3.3
ISSN: 14779226, 14779234
PubMed ID:
23880878
Inorganic Chemistry
Abstract
A new series of ruthenium(II) carbonyl complexes with benzene-based CCC-pincer bis-(carbene) ligands, [((R)CCC(R))Ru(CO)2(X)](0/+) and [((R)CCC(R))Ru(CO)(NN)](+) ((R)CCC(R) = 2,6-bis-(1-alkylimidazolylidene)benzene, R = Me or (n)Bu; X = I, Br, CH3CN, or 6-(aminomethyl)pyridine (ampy); NN = 2·CH3CN, or chelating ampy or bipyridine), was synthesized and fully characterized. X-Ray structure determinations revealed that these eight complexes have pseudo-octahedral configurations around the ruthenium center with the pincer ligand occupying three meridional sites. These complexes prove to be efficient precatalysts demonstrating very good activity and reusability for the transfer hydrogenation of ketones.
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Total citations:
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Citations from 2024:
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(7.69%)
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GOST
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Naziruddin A. R. et al. Ruthenium(ii) carbonyl complexes bearing CCC-pincer bis-(carbene) ligands: synthesis, structures and activities toward recycle transfer hydrogenation reactions // Dalton Transactions. 2013. Vol. 42. No. 36. p. 13161.
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Naziruddin A. R., Huang Z. J., Huang Z., Lai W., Lin W., Wan-Jung Lin, Hwang W. Ruthenium(ii) carbonyl complexes bearing CCC-pincer bis-(carbene) ligands: synthesis, structures and activities toward recycle transfer hydrogenation reactions // Dalton Transactions. 2013. Vol. 42. No. 36. p. 13161.
Cite this
RIS
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TY - JOUR
DO - 10.1039/c3dt51161h
UR - https://doi.org/10.1039/c3dt51161h
TI - Ruthenium(ii) carbonyl complexes bearing CCC-pincer bis-(carbene) ligands: synthesis, structures and activities toward recycle transfer hydrogenation reactions
T2 - Dalton Transactions
AU - Naziruddin, Abbas Raja
AU - Huang, Zhao Jiunn
AU - Huang, Zhao-Jiunn
AU - Lai, Wei-Chih
AU - Lin, Wan‐Jung
AU - Wan-Jung Lin
AU - Hwang, Wen-Shu
PY - 2013
DA - 2013/06/17
PB - Royal Society of Chemistry (RSC)
SP - 13161
IS - 36
VL - 42
PMID - 23880878
SN - 1477-9226
SN - 1477-9234
ER -
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@article{2013_Naziruddin,
author = {Abbas Raja Naziruddin and Zhao Jiunn Huang and Zhao-Jiunn Huang and Wei-Chih Lai and Wan‐Jung Lin and Wan-Jung Lin and Wen-Shu Hwang},
title = {Ruthenium(ii) carbonyl complexes bearing CCC-pincer bis-(carbene) ligands: synthesis, structures and activities toward recycle transfer hydrogenation reactions},
journal = {Dalton Transactions},
year = {2013},
volume = {42},
publisher = {Royal Society of Chemistry (RSC)},
month = {jun},
url = {https://doi.org/10.1039/c3dt51161h},
number = {36},
pages = {13161},
doi = {10.1039/c3dt51161h}
}
Cite this
MLA
Copy
Naziruddin, Abbas Raja, et al. “Ruthenium(ii) carbonyl complexes bearing CCC-pincer bis-(carbene) ligands: synthesis, structures and activities toward recycle transfer hydrogenation reactions.” Dalton Transactions, vol. 42, no. 36, Jun. 2013, p. 13161. https://doi.org/10.1039/c3dt51161h.