On the structure of the thiolated Au6Ag7cluster
Тип публикации: Journal Article
Дата публикации: 2014-07-16
SCImago Q2
WOS Q2
БС2
SJR: 0.641
CiteScore: 5.5
Impact factor: 3
ISSN: 14639076, 14639084
PubMed ID:
25052040
Physical and Theoretical Chemistry
General Physics and Astronomy
Краткое описание
The structure of the recently synthesized mercaptosuccinic acid-protected Au6Ag7(SR)10 cluster has been elucidated by a DFT approach, following an isoelectronic substitution of seven Au atoms by Ag atoms on the [Au13(SR)10](+) cluster. After a systematic search for the lowest-energy isomers, it is demonstrated that its structure comprises one octahedral-like Ag6 core covered by two monoatomic dimer motifs and one Au2Ag1(SR)4 staple-like motif. This result confirms that Ag atoms prefer the inner (core) positions while Au atoms are located on surface staple-like motifs.
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ГОСТ
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Tlahuice Flores A., Tlahuice-Flores A. On the structure of the thiolated Au6Ag7cluster // Physical Chemistry Chemical Physics. 2014. Vol. 16. No. 34. p. 18083.
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Tlahuice Flores A., Tlahuice-Flores A. On the structure of the thiolated Au6Ag7cluster // Physical Chemistry Chemical Physics. 2014. Vol. 16. No. 34. p. 18083.
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TY - JOUR
DO - 10.1039/c4cp02273d
UR - https://doi.org/10.1039/c4cp02273d
TI - On the structure of the thiolated Au6Ag7cluster
T2 - Physical Chemistry Chemical Physics
AU - Tlahuice Flores, Alfredo
AU - Tlahuice-Flores, Alfredo
PY - 2014
DA - 2014/07/16
PB - Royal Society of Chemistry (RSC)
SP - 18083
IS - 34
VL - 16
PMID - 25052040
SN - 1463-9076
SN - 1463-9084
ER -
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BibTex (до 50 авторов)
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@article{2014_Tlahuice Flores,
author = {Alfredo Tlahuice Flores and Alfredo Tlahuice-Flores},
title = {On the structure of the thiolated Au6Ag7cluster},
journal = {Physical Chemistry Chemical Physics},
year = {2014},
volume = {16},
publisher = {Royal Society of Chemistry (RSC)},
month = {jul},
url = {https://doi.org/10.1039/c4cp02273d},
number = {34},
pages = {18083},
doi = {10.1039/c4cp02273d}
}
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MLA
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Tlahuice Flores, Alfredo, and Alfredo Tlahuice-Flores. “On the structure of the thiolated Au6Ag7cluster.” Physical Chemistry Chemical Physics, vol. 16, no. 34, Jul. 2014, p. 18083. https://doi.org/10.1039/c4cp02273d.
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