Catalysis Science and Technology

, том 5 , издание 4 , страницы 2384-2387

Electrocatalytic stereoselective transformation of aldehydes and two molecules of pyrazolin-5-one into (R,R)-bis(spiro-2,4-dihydro-3H-pyrazol-3-one)cyclopropanes

Тип публикации: Journal Article

Дата публикации: 2015-01-30

Royal Society of Chemistry (RSC)

Catalysis Science and Technology

scimago Q2

wos Q2

БС1

SJR: 1.026

CiteScore: 8

Impact factor: 4.2

ISSN: 20444753, 20444761

DOI: 10.1039/C4CY01681E

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Catalysis

Краткое описание

The electrocatalytic direct transformation of aldehydes and two molecules of pyrazolin-5-one in the presence of sodium iodide as a mediator in methanol in an undivided cell results in the stereoselective formation of substituted (R*,R*)-bis(spiro-2,4-dihydro-3H-pyrazol-3-one)cyclopropanes in 65–80% yields. Thus, a unique stereoselective cascade electrocatalytic process has been found. This novel electrocatalytic process opens an efficient and convenient way to synthesize (R*,R*)-bis(spiro-2,4-dihydro-3H-pyrazol-3-one)cyclopropanes – promising compounds for different biomedical applications. Thus, the simple mediatory system can initiate in an undivided cell under mild conditions the electrochemically induced cascade reaction of aldehydes with two molecules of pyrazolin-5-one.

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Elinson M. N. et al. Electrocatalytic stereoselective transformation of aldehydes and two molecules of pyrazolin-5-one into (R*,R*)-bis(spiro-2,4-dihydro-3H-pyrazol-3-one)cyclopropanes // Catalysis Science and Technology. 2015. Vol. 5. No. 4. pp. 2384-2387.

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Elinson M. N., Dorofeeva E. O., Vereshchagin A. N., Nasybullin R. F., Egorov M. P. Electrocatalytic stereoselective transformation of aldehydes and two molecules of pyrazolin-5-one into (R*,R*)-bis(spiro-2,4-dihydro-3H-pyrazol-3-one)cyclopropanes // Catalysis Science and Technology. 2015. Vol. 5. No. 4. pp. 2384-2387.

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TY - JOUR

DO - 10.1039/C4CY01681E

UR - https://doi.org/10.1039/C4CY01681E

TI - Electrocatalytic stereoselective transformation of aldehydes and two molecules of pyrazolin-5-one into (R*,R*)-bis(spiro-2,4-dihydro-3H-pyrazol-3-one)cyclopropanes

T2 - Catalysis Science and Technology

AU - Elinson, M. N.

AU - Dorofeeva, E O

AU - Vereshchagin, A N

AU - Nasybullin, R. F.

AU - Egorov, M. P.

PY - 2015

DA - 2015/01/30

PB - Royal Society of Chemistry (RSC)

SP - 2384-2387

IS - 4

VL - 5

SN - 2044-4753

SN - 2044-4761

ER -

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@article{2015_Elinson,

author = {M. N. Elinson and E O Dorofeeva and A N Vereshchagin and R. F. Nasybullin and M. P. Egorov},

title = {Electrocatalytic stereoselective transformation of aldehydes and two molecules of pyrazolin-5-one into (R*,R*)-bis(spiro-2,4-dihydro-3H-pyrazol-3-one)cyclopropanes},

journal = {Catalysis Science and Technology},

year = {2015},

volume = {5},

publisher = {Royal Society of Chemistry (RSC)},

month = {jan},

url = {https://doi.org/10.1039/C4CY01681E},

number = {4},

pages = {2384--2387},

doi = {10.1039/C4CY01681E}

}

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Elinson, M. N., et al. “Electrocatalytic stereoselective transformation of aldehydes and two molecules of pyrazolin-5-one into (R*,R*)-bis(spiro-2,4-dihydro-3H-pyrazol-3-one)cyclopropanes.” Catalysis Science and Technology, vol. 5, no. 4, Jan. 2015, pp. 2384-2387. https://doi.org/10.1039/C4CY01681E.