Polyethylene glycol (PEG) as a reusable solvent medium for an asymmetric organocatalytic Michael addition. Application to the synthesis of bioactive compounds
Тип публикации: Journal Article
Дата публикации: 2014-03-27
SCImago Q1
Tоп 10% SCImago
WOS Q1
БС1
SJR: 1.811
CiteScore: 16
Impact factor: 10.6
ISSN: 14639262, 14639270
Environmental Chemistry
Pollution
Краткое описание
A highly stereoselective organocatalytic Michael addition of aldehydes to trans-β-nitrostyrenes using PEG as a recyclable solvent medium is presented. The scope of this organocatalytic system is demonstrated by the formation of several Michael adducts in good yields and stereoselectivities. Furthermore, applying this new protocol to acetaldehyde, we have disclosed an easy formal synthesis of (R)-pregabalin, (R)-phenibut and (R)-bacoflen with good yields and outstanding enantioselectivities.
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ГОСТ
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Feu K. S. et al. Polyethylene glycol (PEG) as a reusable solvent medium for an asymmetric organocatalytic Michael addition. Application to the synthesis of bioactive compounds // Green Chemistry. 2014. Vol. 16. No. 6. pp. 3169-3174.
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Feu K. S., F De La Torre A., Silva S., De Moraes Junior M. A. F., Corrêa A. G., Paixao M. Polyethylene glycol (PEG) as a reusable solvent medium for an asymmetric organocatalytic Michael addition. Application to the synthesis of bioactive compounds // Green Chemistry. 2014. Vol. 16. No. 6. pp. 3169-3174.
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TY - JOUR
DO - 10.1039/C4GC00098F
UR - https://doi.org/10.1039/C4GC00098F
TI - Polyethylene glycol (PEG) as a reusable solvent medium for an asymmetric organocatalytic Michael addition. Application to the synthesis of bioactive compounds
T2 - Green Chemistry
AU - Feu, Karla S
AU - F De La Torre, Alexander
AU - Silva, Sandrina
AU - De Moraes Junior, Marco A F
AU - Corrêa, Arlene G
AU - Paixao, Marcio
PY - 2014
DA - 2014/03/27
PB - Royal Society of Chemistry (RSC)
SP - 3169-3174
IS - 6
VL - 16
SN - 1463-9262
SN - 1463-9270
ER -
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BibTex (до 50 авторов)
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@article{2014_Feu,
author = {Karla S Feu and Alexander F De La Torre and Sandrina Silva and Marco A F De Moraes Junior and Arlene G Corrêa and Marcio Paixao},
title = {Polyethylene glycol (PEG) as a reusable solvent medium for an asymmetric organocatalytic Michael addition. Application to the synthesis of bioactive compounds},
journal = {Green Chemistry},
year = {2014},
volume = {16},
publisher = {Royal Society of Chemistry (RSC)},
month = {mar},
url = {https://doi.org/10.1039/C4GC00098F},
number = {6},
pages = {3169--3174},
doi = {10.1039/C4GC00098F}
}
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MLA
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Feu, Karla S., et al. “Polyethylene glycol (PEG) as a reusable solvent medium for an asymmetric organocatalytic Michael addition. Application to the synthesis of bioactive compounds.” Green Chemistry, vol. 16, no. 6, Mar. 2014, pp. 3169-3174. https://doi.org/10.1039/C4GC00098F.
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