Synthesis and magnetic properties of manganese carbonyl complexes with different coordination modes of 3,4,5-triaryl-1,2-diphospholide ligands
Vasili Miluykov
1
,
Ilya A Bezkishko
1
,
Liliya R Kochetkova
1
,
O.N. Kataeva
1
,
Peter Lönnecke
2
,
Anupama Parameswaran
3
,
Y. Krupskaya
3
,
V. E. Kataev
3
,
B. Büchner
3, 4
Publication type: Journal Article
Publication date: 2015-04-24
scimago Q2
wos Q1
SJR: 0.653
CiteScore: 6.0
Impact factor: 3.3
ISSN: 14779226, 14779234
PubMed ID:
25962493
Inorganic Chemistry
Abstract
The set of complexes bis-(μ:η(1),η(1)-3,4,5-triaryl-1,2-diphosphacyclopentadienyl)-bis-(tetracarbonyl manganese(i)) (aryl = C6H5 (), p-FC6H4 (), p-ClC6H4 ()) undergo an irreversible rearrangement to mononuclear 3,4,5-triaryl-1,2-diphosphacymantrenes (). According to quantum-chemical calculations binuclear complexes can be considered to be products of kinetic control and mononuclear species are thermodynamically favorable compounds. The antiferromagnetic intramolecular interaction observed for complexes can be effectively tuned by using substituents in the para-position of the arene ring, whereas mononuclear 1,2-diphosphacymantrenes are diamagnetic.
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Total citations:
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Citations from 2024:
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(11.11%)
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Miluykov V. et al. Synthesis and magnetic properties of manganese carbonyl complexes with different coordination modes of 3,4,5-triaryl-1,2-diphospholide ligands // Dalton Transactions. 2015. Vol. 44. No. 22. pp. 10259-10266.
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Miluykov V., Bezkishko I. A., Kochetkova L. R., Kataeva O., Gerasimova T. I., Katsyuba S. A., Sinyashin O. G., Lönnecke P., Hey-Hawkins E., Parameswaran A., Krupskaya Y., Kataev V. E., Büchner B. Synthesis and magnetic properties of manganese carbonyl complexes with different coordination modes of 3,4,5-triaryl-1,2-diphospholide ligands // Dalton Transactions. 2015. Vol. 44. No. 22. pp. 10259-10266.
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TY - JOUR
DO - 10.1039/c5dt00624d
UR - https://xlink.rsc.org/?DOI=C5DT00624D
TI - Synthesis and magnetic properties of manganese carbonyl complexes with different coordination modes of 3,4,5-triaryl-1,2-diphospholide ligands
T2 - Dalton Transactions
AU - Miluykov, Vasili
AU - Bezkishko, Ilya A
AU - Kochetkova, Liliya R
AU - Kataeva, O.N.
AU - Gerasimova, Tatiana I.
AU - Katsyuba, Sergey A.
AU - Sinyashin, Oleg G.
AU - Lönnecke, Peter
AU - Hey-Hawkins, Evamarie
AU - Parameswaran, Anupama
AU - Krupskaya, Y.
AU - Kataev, V. E.
AU - Büchner, B.
PY - 2015
DA - 2015/04/24
PB - Royal Society of Chemistry (RSC)
SP - 10259-10266
IS - 22
VL - 44
PMID - 25962493
SN - 1477-9226
SN - 1477-9234
ER -
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BibTex (up to 50 authors)
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@article{2015_Miluykov,
author = {Vasili Miluykov and Ilya A Bezkishko and Liliya R Kochetkova and O.N. Kataeva and Tatiana I. Gerasimova and Sergey A. Katsyuba and Oleg G. Sinyashin and Peter Lönnecke and Evamarie Hey-Hawkins and Anupama Parameswaran and Y. Krupskaya and V. E. Kataev and B. Büchner},
title = {Synthesis and magnetic properties of manganese carbonyl complexes with different coordination modes of 3,4,5-triaryl-1,2-diphospholide ligands},
journal = {Dalton Transactions},
year = {2015},
volume = {44},
publisher = {Royal Society of Chemistry (RSC)},
month = {apr},
url = {https://xlink.rsc.org/?DOI=C5DT00624D},
number = {22},
pages = {10259--10266},
doi = {10.1039/c5dt00624d}
}
Cite this
MLA
Copy
Miluykov, Vasili, et al. “Synthesis and magnetic properties of manganese carbonyl complexes with different coordination modes of 3,4,5-triaryl-1,2-diphospholide ligands.” Dalton Transactions, vol. 44, no. 22, Apr. 2015, pp. 10259-10266. https://xlink.rsc.org/?DOI=C5DT00624D.