Chemical Communications, volume 53, issue 1, pages 216-219
Palladium-catalyzed oxidative cyclization of aniline-tethered alkylidenecyclopropanes with O2: a facile protocol to selectively synthesize 2- and 3-vinylindoles
Publication type: Journal Article
Publication date: 2017-01-01
Journal:
Chemical Communications
Q1
Q2
SJR: 1.133
CiteScore: 8.6
Impact factor: 4.3
ISSN: 13597345, 1364548X
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Abstract
A novel palladium-catalyzed oxidative cyclization of aniline-tethered alkylidenecyclopropanes using molecular oxygen as the terminal oxidant through β-carbon elimination of aminopalladation intermediates is disclosed. The reaction opens up an effective way to obtain a series of 2- and 3-vinylindoles which are important synthetic intermediates in many natural indole derivatives.
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Cao B. et al. Palladium-catalyzed oxidative cyclization of aniline-tethered alkylidenecyclopropanes with O2: a facile protocol to selectively synthesize 2- and 3-vinylindoles // Chemical Communications. 2017. Vol. 53. No. 1. pp. 216-219.
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Cao B., Simaan M., Marek I., Wei Yin 尹., Shi M. Palladium-catalyzed oxidative cyclization of aniline-tethered alkylidenecyclopropanes with O2: a facile protocol to selectively synthesize 2- and 3-vinylindoles // Chemical Communications. 2017. Vol. 53. No. 1. pp. 216-219.
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TY - JOUR
DO - 10.1039/c6cc08731k
UR - https://doi.org/10.1039/c6cc08731k
TI - Palladium-catalyzed oxidative cyclization of aniline-tethered alkylidenecyclopropanes with O2: a facile protocol to selectively synthesize 2- and 3-vinylindoles
T2 - Chemical Communications
AU - Cao, Bo
AU - Simaan, Marwan
AU - Marek, Ilan
AU - Wei Yin, 尹维
AU - Shi, Min
PY - 2017
DA - 2017/01/01
PB - Royal Society of Chemistry (RSC)
SP - 216-219
IS - 1
VL - 53
SN - 1359-7345
SN - 1364-548X
ER -
Cite this
BibTex (up to 50 authors)
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@article{2017_Cao,
author = {Bo Cao and Marwan Simaan and Ilan Marek and 尹维 Wei Yin and Min Shi},
title = {Palladium-catalyzed oxidative cyclization of aniline-tethered alkylidenecyclopropanes with O2: a facile protocol to selectively synthesize 2- and 3-vinylindoles},
journal = {Chemical Communications},
year = {2017},
volume = {53},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/c6cc08731k},
number = {1},
pages = {216--219},
doi = {10.1039/c6cc08731k}
}
Cite this
MLA
Copy
Cao, Bo, et al. “Palladium-catalyzed oxidative cyclization of aniline-tethered alkylidenecyclopropanes with O2: a facile protocol to selectively synthesize 2- and 3-vinylindoles.” Chemical Communications, vol. 53, no. 1, Jan. 2017, pp. 216-219. https://doi.org/10.1039/c6cc08731k.