Chemical Communications, volume 53, issue 1, pages 216-219

Palladium-catalyzed oxidative cyclization of aniline-tethered alkylidenecyclopropanes with O2: a facile protocol to selectively synthesize 2- and 3-vinylindoles

Bo Cao 1
Marwan Simaan 2
Ilan Marek 2
尹维 Wei Yin 3
Min Shi 1, 3
Publication typeJournal Article
Publication date2017-01-01
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor4.9
ISSN13597345, 1364548X
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Abstract
A novel palladium-catalyzed oxidative cyclization of aniline-tethered alkylidenecyclopropanes using molecular oxygen as the terminal oxidant through β-carbon elimination of aminopalladation intermediates is disclosed. The reaction opens up an effective way to obtain a series of 2- and 3-vinylindoles which are important synthetic intermediates in many natural indole derivatives.

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GOST |
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GOST Copy
Cao B. et al. Palladium-catalyzed oxidative cyclization of aniline-tethered alkylidenecyclopropanes with O2: a facile protocol to selectively synthesize 2- and 3-vinylindoles // Chemical Communications. 2017. Vol. 53. No. 1. pp. 216-219.
GOST all authors (up to 50) Copy
Cao B., Simaan M., Marek I., Wei Yin 尹., Shi M. Palladium-catalyzed oxidative cyclization of aniline-tethered alkylidenecyclopropanes with O2: a facile protocol to selectively synthesize 2- and 3-vinylindoles // Chemical Communications. 2017. Vol. 53. No. 1. pp. 216-219.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1039/c6cc08731k
UR - https://doi.org/10.1039/c6cc08731k
TI - Palladium-catalyzed oxidative cyclization of aniline-tethered alkylidenecyclopropanes with O2: a facile protocol to selectively synthesize 2- and 3-vinylindoles
T2 - Chemical Communications
AU - Simaan, Marwan
AU - Cao, Bo
AU - Marek, Ilan
AU - Wei Yin, 尹维
AU - Shi, Min
PY - 2017
DA - 2017/01/01 00:00:00
PB - Royal Society of Chemistry (RSC)
SP - 216-219
IS - 1
VL - 53
SN - 1359-7345
SN - 1364-548X
ER -
BibTex |
Cite this
BibTex Copy
@article{2017_Cao,
author = {Marwan Simaan and Bo Cao and Ilan Marek and 尹维 Wei Yin and Min Shi},
title = {Palladium-catalyzed oxidative cyclization of aniline-tethered alkylidenecyclopropanes with O2: a facile protocol to selectively synthesize 2- and 3-vinylindoles},
journal = {Chemical Communications},
year = {2017},
volume = {53},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/c6cc08731k},
number = {1},
pages = {216--219},
doi = {10.1039/c6cc08731k}
}
MLA
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MLA Copy
Cao, Bo, et al. “Palladium-catalyzed oxidative cyclization of aniline-tethered alkylidenecyclopropanes with O2: a facile protocol to selectively synthesize 2- and 3-vinylindoles.” Chemical Communications, vol. 53, no. 1, Jan. 2017, pp. 216-219. https://doi.org/10.1039/c6cc08731k.
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