PdZn catalysts for CO2 hydrogenation to methanol using chemical vapour impregnation (CVI)
Тип публикации: Journal Article
Дата публикации: 2017-01-01
scimago Q1
wos Q3
БС1
SJR: 0.878
CiteScore: 6
Impact factor: 3.1
ISSN: 13645498, 13596640
PubMed ID:
28180215
Physical and Theoretical Chemistry
Краткое описание
The formation of PdZn bimetallic alloys on ZnO, TiO2 and Al2O3 supports was investigated, together with the effect of alloy formation on the CO2 hydrogenation reaction. The chemical vapour impregnation (CVI) method produced PdZn nanoparticles with diameters of 3–6 nm. X-ray photoelectron spectroscopy and X-ray diffraction revealed the changes in the structure of the PdZn alloy that help stabilise formate intermediates during methanol synthesis. PdZn supported on TiO2 exhibits high methanol productivity of 1730 mmol kgcat−1 h−1 that is associated with the high dispersion of the supported PdZn alloy.
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ГОСТ
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Bahruji H. et al. PdZn catalysts for CO2 hydrogenation to methanol using chemical vapour impregnation (CVI) // Faraday Discussions. 2017. Vol. 197. pp. 309-324.
ГОСТ со всеми авторами (до 50)
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Bahruji H., Bowker M., JONES W., Hayward J., Ruiz Esquius J., Morgan D. J., Hutchings G. PdZn catalysts for CO2 hydrogenation to methanol using chemical vapour impregnation (CVI) // Faraday Discussions. 2017. Vol. 197. pp. 309-324.
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RIS
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TY - JOUR
DO - 10.1039/c6fd00189k
UR - https://doi.org/10.1039/c6fd00189k
TI - PdZn catalysts for CO2 hydrogenation to methanol using chemical vapour impregnation (CVI)
T2 - Faraday Discussions
AU - Bahruji, H
AU - Bowker, M.
AU - JONES, W
AU - Hayward, J
AU - Ruiz Esquius, J
AU - Morgan, D. J.
AU - Hutchings, G.J
PY - 2017
DA - 2017/01/01
PB - Royal Society of Chemistry (RSC)
SP - 309-324
VL - 197
PMID - 28180215
SN - 1364-5498
SN - 1359-6640
ER -
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BibTex (до 50 авторов)
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@article{2017_Bahruji,
author = {H Bahruji and M. Bowker and W JONES and J Hayward and J Ruiz Esquius and D. J. Morgan and G.J Hutchings},
title = {PdZn catalysts for CO2 hydrogenation to methanol using chemical vapour impregnation (CVI)},
journal = {Faraday Discussions},
year = {2017},
volume = {197},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/c6fd00189k},
pages = {309--324},
doi = {10.1039/c6fd00189k}
}