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Spontaneous chiral resolution and hierarchical directing effects of two-winged propeller-like SDAs on the construction of noncentrosymmetric iodoargentates/iodocuprates
Тип публикации: Journal Article
Дата публикации: 2016-09-09
scimago Q1
wos Q2
БС1
SJR: 0.777
CiteScore: 7.6
Impact factor: 4.6
ISSN: 20462069
General Chemistry
General Chemical Engineering
Краткое описание
Directed by in situ benzylated pyridine derivatives with potential conformational chirality, four inorganic–organic hybrids, [BCP]2[Ag4I6] (1), [BCP][CuI2CuIII5]·2H2O (2), [BQL][Ag4I5] (3), [BQL]2[Cu5I7] (4) (BCP+ = N-benzyl-4-cyanopyridinium, BQL+ = N-benzyl-quinolinium) have been synthesized solvothermally. The contrast between spontaneous chiral resolution for BCP+ in 1 and 2 and racemic BQL+ aggregates in 3 and 4, and remarkable structural correlations between organic and inorganic species exhibit interesting chiral structure directing effects, which are mainly attributed to the variation of organic motif, substituent, and consequently flexible supramolecular assemblies, as well as hierarchical matching ability between inorganic and organic species. 1 also exhibits second harmonic generation (SHG) responses in both visible and ultraviolet regions.
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Hao P. et al. Spontaneous chiral resolution and hierarchical directing effects of two-winged propeller-like SDAs on the construction of noncentrosymmetric iodoargentates/iodocuprates // RSC Advances. 2016. Vol. 6. No. 90. pp. 87628-87636.
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Hao P., Qiao Y., Yu T., Shen J., Dai D., Fu Y. Spontaneous chiral resolution and hierarchical directing effects of two-winged propeller-like SDAs on the construction of noncentrosymmetric iodoargentates/iodocuprates // RSC Advances. 2016. Vol. 6. No. 90. pp. 87628-87636.
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TY - JOUR
DO - 10.1039/c6ra15159k
UR - https://doi.org/10.1039/c6ra15159k
TI - Spontaneous chiral resolution and hierarchical directing effects of two-winged propeller-like SDAs on the construction of noncentrosymmetric iodoargentates/iodocuprates
T2 - RSC Advances
AU - Hao, Pengfei
AU - Qiao, Yanrong
AU - Yu, Tanlai
AU - Shen, Junju
AU - Dai, Dongting
AU - Fu, Yunlong
PY - 2016
DA - 2016/09/09
PB - Royal Society of Chemistry (RSC)
SP - 87628-87636
IS - 90
VL - 6
SN - 2046-2069
ER -
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@article{2016_Hao,
author = {Pengfei Hao and Yanrong Qiao and Tanlai Yu and Junju Shen and Dongting Dai and Yunlong Fu},
title = {Spontaneous chiral resolution and hierarchical directing effects of two-winged propeller-like SDAs on the construction of noncentrosymmetric iodoargentates/iodocuprates},
journal = {RSC Advances},
year = {2016},
volume = {6},
publisher = {Royal Society of Chemistry (RSC)},
month = {sep},
url = {https://doi.org/10.1039/c6ra15159k},
number = {90},
pages = {87628--87636},
doi = {10.1039/c6ra15159k}
}
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Hao, Pengfei, et al. “Spontaneous chiral resolution and hierarchical directing effects of two-winged propeller-like SDAs on the construction of noncentrosymmetric iodoargentates/iodocuprates.” RSC Advances, vol. 6, no. 90, Sep. 2016, pp. 87628-87636. https://doi.org/10.1039/c6ra15159k.