Pillar[5]arene-based [1]rotaxane: high-yield synthesis, characterization and application in Knoevenagel reaction.
Xu Sheng Du
1
,
Chun Yu Wang
2
,
Qiong Jia
1
,
Rong Deng
1
,
Hua Sheng Tian
1
,
Houyu Zhang
2
,
Kamel Meguellati
1
,
Ying-Wei Yang
1
Publication type: Journal Article
Publication date: 2017-04-12
scimago Q1
wos Q2
SJR: 1.037
CiteScore: 7.4
Impact factor: 4.2
ISSN: 13597345, 1364548X
PubMed ID:
28447692
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Abstract
We report a quantitative synthetic strategy of a [1]rotaxane from a representative pseudo[1]rotaxane. The structure of the [1]rotaxane was characterized by 1H NMR, 13C NMR, 2D NMR, mass spectroscopy, and melting point, and its optimized geometry in CHCl3 by theoretical calculation at the B3LYP/6-31G(D) level using the PCM model matched well with 2D NOESY. This [1]rotaxane proves to be a good catalyst for the Knoevenagel reaction in CHCl3, which follows second order kinetics.
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Total citations:
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Citations from 2024:
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(9%)
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GOST
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Du X. S. et al. Pillar[5]arene-based [1]rotaxane: high-yield synthesis, characterization and application in Knoevenagel reaction. // Chemical Communications. 2017. Vol. 53. No. 38. pp. 5326-5329.
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Du X. S., Wang C. Yu., Jia Q., Deng R., Tian H. S., Zhang H., Meguellati K., Yang Y. Pillar[5]arene-based [1]rotaxane: high-yield synthesis, characterization and application in Knoevenagel reaction. // Chemical Communications. 2017. Vol. 53. No. 38. pp. 5326-5329.
Cite this
RIS
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TY - JOUR
DO - 10.1039/C7CC02364B
UR - https://doi.org/10.1039/C7CC02364B
TI - Pillar[5]arene-based [1]rotaxane: high-yield synthesis, characterization and application in Knoevenagel reaction.
T2 - Chemical Communications
AU - Du, Xu Sheng
AU - Wang, Chun Yu
AU - Jia, Qiong
AU - Deng, Rong
AU - Tian, Hua Sheng
AU - Zhang, Houyu
AU - Meguellati, Kamel
AU - Yang, Ying-Wei
PY - 2017
DA - 2017/04/12
PB - Royal Society of Chemistry (RSC)
SP - 5326-5329
IS - 38
VL - 53
PMID - 28447692
SN - 1359-7345
SN - 1364-548X
ER -
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BibTex (up to 50 authors)
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@article{2017_Du,
author = {Xu Sheng Du and Chun Yu Wang and Qiong Jia and Rong Deng and Hua Sheng Tian and Houyu Zhang and Kamel Meguellati and Ying-Wei Yang},
title = {Pillar[5]arene-based [1]rotaxane: high-yield synthesis, characterization and application in Knoevenagel reaction.},
journal = {Chemical Communications},
year = {2017},
volume = {53},
publisher = {Royal Society of Chemistry (RSC)},
month = {apr},
url = {https://doi.org/10.1039/C7CC02364B},
number = {38},
pages = {5326--5329},
doi = {10.1039/C7CC02364B}
}
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MLA
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Du, Xu Sheng, et al. “Pillar[5]arene-based [1]rotaxane: high-yield synthesis, characterization and application in Knoevenagel reaction..” Chemical Communications, vol. 53, no. 38, Apr. 2017, pp. 5326-5329. https://doi.org/10.1039/C7CC02364B.