Silsesquioxane cages as fluoride sensors.
Supphachok Chanmungkalakul
1
,
Vuthichai Ervithayasuporn
1
,
Sasikarn Hanprasit
1
,
Manlika Masik
1
,
Nicha Prigyai
1
,
Suda Kiatkamjornwong
2, 3
Publication type: Journal Article
Publication date: 2017-10-17
scimago Q1
wos Q2
SJR: 1.037
CiteScore: 7.4
Impact factor: 4.2
ISSN: 13597345, 1364548X
PubMed ID:
29072723
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Abstract
Pyrene functionalized silsesquioxane cages (PySQ) not only provide significant fluorescence from pyrene-pyrene excimers with a very large Stokes shift (Δλ = 143 nm, 69 930 cm-1) in DMSO but also exhibit fluoride capture results coincidentally with a π-π* fluorescence enhancement. On the other hand, PySQ-F- in THF significantly exhibits π-π* fluorescence quenching and a color change can be observed with the naked eye from light yellow to deep orange by forming a charge-transfer (CT) complex among the pyrenyl rings. Moreover, PySQ selectively captures F- with a response time of <2 min and with a very low detection limit (1.61 ppb), while 19F NMR is used to confirm encapsulation of F- with Δδ = 19 ppm.
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GOST
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Chanmungkalakul S. et al. Silsesquioxane cages as fluoride sensors. // Chemical Communications. 2017. Vol. 53. No. 89. pp. 12108-12111.
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Chanmungkalakul S., Ervithayasuporn V., Hanprasit S., Masik M., Prigyai N., Kiatkamjornwong S. Silsesquioxane cages as fluoride sensors. // Chemical Communications. 2017. Vol. 53. No. 89. pp. 12108-12111.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/C7CC06647C
UR - https://doi.org/10.1039/C7CC06647C
TI - Silsesquioxane cages as fluoride sensors.
T2 - Chemical Communications
AU - Chanmungkalakul, Supphachok
AU - Ervithayasuporn, Vuthichai
AU - Hanprasit, Sasikarn
AU - Masik, Manlika
AU - Prigyai, Nicha
AU - Kiatkamjornwong, Suda
PY - 2017
DA - 2017/10/17
PB - Royal Society of Chemistry (RSC)
SP - 12108-12111
IS - 89
VL - 53
PMID - 29072723
SN - 1359-7345
SN - 1364-548X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2017_Chanmungkalakul,
author = {Supphachok Chanmungkalakul and Vuthichai Ervithayasuporn and Sasikarn Hanprasit and Manlika Masik and Nicha Prigyai and Suda Kiatkamjornwong},
title = {Silsesquioxane cages as fluoride sensors.},
journal = {Chemical Communications},
year = {2017},
volume = {53},
publisher = {Royal Society of Chemistry (RSC)},
month = {oct},
url = {https://doi.org/10.1039/C7CC06647C},
number = {89},
pages = {12108--12111},
doi = {10.1039/C7CC06647C}
}
Cite this
MLA
Copy
Chanmungkalakul, Supphachok, et al. “Silsesquioxane cages as fluoride sensors..” Chemical Communications, vol. 53, no. 89, Oct. 2017, pp. 12108-12111. https://doi.org/10.1039/C7CC06647C.