volume 46 issue 27 pages 8709-8715

Functionalized vinylsilanes via highly efficient and recyclable Pt-nanoparticle catalysed hydrosilylation of alkynes.

Bhanu P. S. Chauhan 1
Alok Sarkar 1
1
 
Engineered Nanomaterials Laboratory, Department of Chemistry, William Paterson University, 300 Pompton Road, Wayne, New Jersey 07470-2103, USA
Publication typeJournal Article
Publication date2017-04-10
scimago Q2
wos Q1
SJR0.653
CiteScore6.0
Impact factor3.3
ISSN14779226, 14779234
PubMed ID:  28426075
Inorganic Chemistry
Abstract
A mild, selective and facile synthesis of vinylsilanes via a recyclable platinum nanoparticle catalysed hydrosilylation of alkynes is reported. Various functionalized alkynes are selectively hydrosilylated to furnish functional β-E vinylsilanes in high yields. The catalytic effectiveness, ease of catalyst recovery and recyclability of the polysiloxane stabilized Pt-nanoparticle catalyst are the major achievements of this work. Detailed in situ characterization using Electron Microscopy and controlled poisoning experiments supports the participation of Pt-nanoparticles as active catalysts.
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Chauhan B. P. S., Sarkar A. Functionalized vinylsilanes via highly efficient and recyclable Pt-nanoparticle catalysed hydrosilylation of alkynes. // Dalton Transactions. 2017. Vol. 46. No. 27. pp. 8709-8715.
GOST all authors (up to 50) Copy
Chauhan B. P. S., Sarkar A. Functionalized vinylsilanes via highly efficient and recyclable Pt-nanoparticle catalysed hydrosilylation of alkynes. // Dalton Transactions. 2017. Vol. 46. No. 27. pp. 8709-8715.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1039/C7DT00544J
UR - https://doi.org/10.1039/C7DT00544J
TI - Functionalized vinylsilanes via highly efficient and recyclable Pt-nanoparticle catalysed hydrosilylation of alkynes.
T2 - Dalton Transactions
AU - Chauhan, Bhanu P. S.
AU - Sarkar, Alok
PY - 2017
DA - 2017/04/10
PB - Royal Society of Chemistry (RSC)
SP - 8709-8715
IS - 27
VL - 46
PMID - 28426075
SN - 1477-9226
SN - 1477-9234
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2017_Chauhan,
author = {Bhanu P. S. Chauhan and Alok Sarkar},
title = {Functionalized vinylsilanes via highly efficient and recyclable Pt-nanoparticle catalysed hydrosilylation of alkynes.},
journal = {Dalton Transactions},
year = {2017},
volume = {46},
publisher = {Royal Society of Chemistry (RSC)},
month = {apr},
url = {https://doi.org/10.1039/C7DT00544J},
number = {27},
pages = {8709--8715},
doi = {10.1039/C7DT00544J}
}
MLA
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MLA Copy
Chauhan, Bhanu P. S., and Alok Sarkar. “Functionalized vinylsilanes via highly efficient and recyclable Pt-nanoparticle catalysed hydrosilylation of alkynes..” Dalton Transactions, vol. 46, no. 27, Apr. 2017, pp. 8709-8715. https://doi.org/10.1039/C7DT00544J.