Dalton Transactions, volume 47, issue 13, pages 4524-4533
The peculiarities of complex formation and energy transfer processes in lanthanide complexes with 2-(tosylamino)-benzylidene-N-benzoylhydrazone.
Publication type: Journal Article
Publication date: 2018-02-19
Journal:
Dalton Transactions
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 4
ISSN: 14779226, 14779234
Inorganic Chemistry
Abstract
Depending on the local excess of lanthanide ions (Ln = Lu, Yb, Er, Dy, Tb, Gd, Eu, Nd) or 2-(tosylamino)-benzylidene-N-benzoylhydrazone (H2L), lanthanide complexes, containing either a mono-deprotonated ligand (Ln(HL)2X, X = Cl, NO3) or both mono- and dideprotonated ligands (Ln(L)(HL)), were preparatively obtained. The crystal structures of Lu(HL)2Cl, Yb(L)(HL)(H2O)2, Yb(L)(HL)(EtOH)2(H2O) and Er(L)(HL), determined by single crystal diffraction data or from powder diffraction data using Rietveld refinement, have shown the surprising resemblance. The study of luminescence temperature dependence of Eu(HL)2Cl and Eu(L)(HL) showed that europium luminescence is quenched by thermally-activated 5D0 → T1 energy transfer. Luminescent thermometers based on these complexes demonstrated the sensitivity of up to 7.7% at 85 K which is the highest value above liquid-nitrogen temperatures obtained to date.
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Kovalenko A. et al. The peculiarities of complex formation and energy transfer processes in lanthanide complexes with 2-(tosylamino)-benzylidene-N-benzoylhydrazone. // Dalton Transactions. 2018. Vol. 47. No. 13. pp. 4524-4533.
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Kovalenko A., Bushmarinov I. S., Burlov A., Lepnev L. S., Ilina E. G., Utochnikova V. The peculiarities of complex formation and energy transfer processes in lanthanide complexes with 2-(tosylamino)-benzylidene-N-benzoylhydrazone. // Dalton Transactions. 2018. Vol. 47. No. 13. pp. 4524-4533.
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TY - JOUR
DO - 10.1039/C7DT04387B
UR - https://doi.org/10.1039%2FC7DT04387B
TI - The peculiarities of complex formation and energy transfer processes in lanthanide complexes with 2-(tosylamino)-benzylidene-N-benzoylhydrazone.
T2 - Dalton Transactions
AU - Burlov, A.S
AU - Lepnev, Leonid S.
AU - Utochnikova, Valentina
AU - Ilina, Elena G
AU - Kovalenko, Anton
AU - Bushmarinov, I. S.
PY - 2018
DA - 2018/02/19 00:00:00
PB - Royal Society of Chemistry (RSC)
SP - 4524-4533
IS - 13
VL - 47
SN - 1477-9226
SN - 1477-9234
ER -
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@article{2018_Kovalenko
author = {A.S Burlov and Leonid S. Lepnev and Valentina Utochnikova and Elena G Ilina and Anton Kovalenko and I. S. Bushmarinov},
title = {The peculiarities of complex formation and energy transfer processes in lanthanide complexes with 2-(tosylamino)-benzylidene-N-benzoylhydrazone.},
journal = {Dalton Transactions},
year = {2018},
volume = {47},
publisher = {Royal Society of Chemistry (RSC)},
month = {feb},
url = {https://doi.org/10.1039%2FC7DT04387B},
number = {13},
pages = {4524--4533},
doi = {10.1039/C7DT04387B}
}
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Kovalenko, Anton, et al. “The peculiarities of complex formation and energy transfer processes in lanthanide complexes with 2-(tosylamino)-benzylidene-N-benzoylhydrazone..” Dalton Transactions, vol. 47, no. 13, Feb. 2018, pp. 4524-4533. https://doi.org/10.1039%2FC7DT04387B.