Journal of Materials Chemistry A, volume 5, issue 20, pages 9917-9928
Synthesis of hard carbon from argan shells for Na-ion batteries
Mouad Dahbi
1, 2
,
Manami Kiso
1
,
Kei Kubota
1, 2
,
Tatsuo Horiba
1
,
Tarik Chafik
3
,
Kazuo Hida
4
,
Takashi Matsuyama
4
,
Shin-ichi Komaba
1, 2
3
Laboratory LGCVR (UAE/FSTL01), Faculty of Sciences and Techniques, University Abdelmalek Essaadi, Tangier, Morocco
|
4
Nippon A&L Inc., Osaka 554-8558, Japan
|
Publication type: Journal Article
Publication date: 2017-04-18
Journal:
Journal of Materials Chemistry A
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 11.9
ISSN: 20507488, 20507496, 09599428, 13645501
General Chemistry
General Materials Science
Renewable Energy, Sustainability and the Environment
Abstract
Hard carbon is an attractive material for negative electrodes in sodium-ion batteries. Herein, we report a new hard carbon synthesized via carbonization of argan shell biomass, which delivers an enhanced capacity higher than 330 mA h g−1 based upon reversible sodium insertion. We prepared hard carbon under different high-temperature treatment and biomass pretreatment conditions. The graphitization degree of the hard carbon increased as the carbonization temperature increased; simultaneously, the reversible capacity for sodium storage was significantly influenced by the carbonization temperature. Structural characterization revealed differences in the structures of the hard carbons synthesized at different carbonization temperatures, which elucidates the correlation between the increased capacity and the micropore size available for sodium storage. The composite electrodes containing the argan hard carbons with a sodium polyacrylate binder were tested in non-aqueous sodium half cells. The electrodes delivered reversible capacities as high as 300 mA h g−1 at a current density of 25 mA g−1 with superior reversibility and capacity retention of 94.1% after 70 cycles. By carbonization of argan shell biomass treated with HCl aqueous solution, we successfully demonstrated a higher reversible capacity of 333 mA h g−1 and an excellent capacity retention of 96.0% after 100 cycles.
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Citations by publishers
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Dahbi M. et al. Synthesis of hard carbon from argan shells for Na-ion batteries // Journal of Materials Chemistry A. 2017. Vol. 5. No. 20. pp. 9917-9928.
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Dahbi M., Kiso M., Kubota K., Horiba T., Chafik T., Hida K., Matsuyama T., Komaba S. Synthesis of hard carbon from argan shells for Na-ion batteries // Journal of Materials Chemistry A. 2017. Vol. 5. No. 20. pp. 9917-9928.
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TY - JOUR
DO - 10.1039/C7TA01394A
UR - https://doi.org/10.1039/C7TA01394A
TI - Synthesis of hard carbon from argan shells for Na-ion batteries
T2 - Journal of Materials Chemistry A
AU - Dahbi, Mouad
AU - Kiso, Manami
AU - Horiba, Tatsuo
AU - Hida, Kazuo
AU - Matsuyama, Takashi
AU - Komaba, Shin-ichi
AU - Kubota, Kei
AU - Chafik, Tarik
PY - 2017
DA - 2017/04/18 00:00:00
PB - Royal Society of Chemistry (RSC)
SP - 9917-9928
IS - 20
VL - 5
SN - 2050-7488
SN - 2050-7496
SN - 0959-9428
SN - 1364-5501
ER -
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@article{2017_Dahbi,
author = {Mouad Dahbi and Manami Kiso and Tatsuo Horiba and Kazuo Hida and Takashi Matsuyama and Shin-ichi Komaba and Kei Kubota and Tarik Chafik},
title = {Synthesis of hard carbon from argan shells for Na-ion batteries},
journal = {Journal of Materials Chemistry A},
year = {2017},
volume = {5},
publisher = {Royal Society of Chemistry (RSC)},
month = {apr},
url = {https://doi.org/10.1039/C7TA01394A},
number = {20},
pages = {9917--9928},
doi = {10.1039/C7TA01394A}
}
Cite this
MLA
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Dahbi, Mouad, et al. “Synthesis of hard carbon from argan shells for Na-ion batteries.” Journal of Materials Chemistry A, vol. 5, no. 20, Apr. 2017, pp. 9917-9928. https://doi.org/10.1039/C7TA01394A.
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