Chemical Communications, volume 54, issue 74, pages 10503-10506

Catalyst-free geminal aminofluorination of ortho-sulfonamide-tethered alkylidenecyclopropanes via a Wagner–Meerwein rearrangement

Xing Fan ¹

Wang Qiang ²

尹维 Wei Yin ¹

Min Shi ^{1, 2}

Hide authors affiliations Show authors affiliations: 2 affiliations

State Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, University of Chinese Academy of Sciences, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China

University of Chinese Academy of Sciences

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences

Key Laboratory for Advanced Materials and Institute of Fine Chemicals, School of Chemistry & Molecular Engineering, East China University of Science and Technology, Meilong Road No. 130, Shanghai 200237, China |

Publication type: Journal Article

Publication date: 2018-08-20

Royal Society of Chemistry (RSC)

Journal: Chemical Communications

SJR: 1.133

CiteScore: 8.6

Impact factor: 4.3

ISSN: 13597345, 1364548X

DOI: 10.1039/c8cc05634j

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Materials Chemistry

Metals and Alloys

Surfaces, Coatings and Films

General Chemistry

Ceramics and Composites

Electronic, Optical and Magnetic Materials

Catalysis

Abstract

A catalyst-free intramolecular geminal aminofluorination of ortho-sulfonamide-tethered alkylidenecyclopropanes has been developed to forge fluorinated cyclobuta[b]indoline derivatives. A polycyclic multi-fluorinated byproduct was also formed through a Ritter-type reaction in some cases.

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GOST |

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GOST Copy

Fan X. et al. Catalyst-free geminal aminofluorination of ortho-sulfonamide-tethered alkylidenecyclopropanes via a Wagner–Meerwein rearrangement // Chemical Communications. 2018. Vol. 54. No. 74. pp. 10503-10506.

GOST all authors (up to 50) Copy

Fan X., Qiang W., Wei Yin 尹., Shi M. Catalyst-free geminal aminofluorination of ortho-sulfonamide-tethered alkylidenecyclopropanes via a Wagner–Meerwein rearrangement // Chemical Communications. 2018. Vol. 54. No. 74. pp. 10503-10506.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1039/c8cc05634j

UR - https://doi.org/10.1039/c8cc05634j

TI - Catalyst-free geminal aminofluorination of ortho-sulfonamide-tethered alkylidenecyclopropanes via a Wagner–Meerwein rearrangement

T2 - Chemical Communications

AU - Fan, Xing

AU - Qiang, Wang

AU - Wei Yin, 尹维

AU - Shi, Min

PY - 2018

DA - 2018/08/20

PB - Royal Society of Chemistry (RSC)

SP - 10503-10506

IS - 74

VL - 54

SN - 1359-7345

SN - 1364-548X

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2018_Fan,

author = {Xing Fan and Wang Qiang and 尹维 Wei Yin and Min Shi},

title = {Catalyst-free geminal aminofluorination of ortho-sulfonamide-tethered alkylidenecyclopropanes via a Wagner–Meerwein rearrangement},

journal = {Chemical Communications},

year = {2018},

volume = {54},

publisher = {Royal Society of Chemistry (RSC)},

month = {aug},

url = {https://doi.org/10.1039/c8cc05634j},

number = {74},

pages = {10503--10506},

doi = {10.1039/c8cc05634j}

}

MLA

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MLA Copy

Fan, Xing, et al. “Catalyst-free geminal aminofluorination of ortho-sulfonamide-tethered alkylidenecyclopropanes via a Wagner–Meerwein rearrangement.” Chemical Communications, vol. 54, no. 74, Aug. 2018, pp. 10503-10506. https://doi.org/10.1039/c8cc05634j.

Found error?

Publisher

Royal Society of Chemistry (RSC)

Journal

Chemical Communications

SJR

1.133

CiteScore

8.6

Impact factor

4.3

ISSN

13597345 (Print)

1364548X (Electronic)