Rapid assembly of cyclopentene spiroisoindolinones via a rhodium-catalysed redox-neutral cascade reaction.
Tingting Yuan
1
,
Chao Pi
1, 2
,
Chang You
1
,
Xiuling Cui
1, 2
,
Sidong Du
1
,
Ting Wan
1
,
Yangjie Wu
1
1
Publication type: Journal Article
Publication date: 2019-01-01
scimago Q1
wos Q2
SJR: 1.037
CiteScore: 7.4
Impact factor: 4.2
ISSN: 13597345, 1364548X
PubMed ID:
30411097
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Abstract
An unprecedented strategy of a rhodium-catalysed redox-neutral cascade reaction starting from benzamides and cyclopropenones via addition of a C-H bond into a polar carbonyl group for the rapid assembly of cyclopentene spiroisoindolinones has been developed. Water was produced as the sole by-product. Metal migration and abstraction of a H-atom from the arylcyclopropenone's aromatic ring are the key steps in building the spirocycle. Two C-C bonds, one C-N bond and an N-substituted quaternary carbon center were formed sequentially in a one pot manner.
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75
Total citations:
75
Citations from 2025:
8
(10.67%)
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GOST
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Yuan T. et al. Rapid assembly of cyclopentene spiroisoindolinones via a rhodium-catalysed redox-neutral cascade reaction. // Chemical Communications. 2019. Vol. 55. No. 2. pp. 163-166.
GOST all authors (up to 50)
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Yuan T., Pi C., You C., Cui X., Du S., Wan T., Wu Y. Rapid assembly of cyclopentene spiroisoindolinones via a rhodium-catalysed redox-neutral cascade reaction. // Chemical Communications. 2019. Vol. 55. No. 2. pp. 163-166.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/C8CC08081J
UR - https://doi.org/10.1039/C8CC08081J
TI - Rapid assembly of cyclopentene spiroisoindolinones via a rhodium-catalysed redox-neutral cascade reaction.
T2 - Chemical Communications
AU - Yuan, Tingting
AU - Pi, Chao
AU - You, Chang
AU - Cui, Xiuling
AU - Du, Sidong
AU - Wan, Ting
AU - Wu, Yangjie
PY - 2019
DA - 2019/01/01
PB - Royal Society of Chemistry (RSC)
SP - 163-166
IS - 2
VL - 55
PMID - 30411097
SN - 1359-7345
SN - 1364-548X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2019_Yuan,
author = {Tingting Yuan and Chao Pi and Chang You and Xiuling Cui and Sidong Du and Ting Wan and Yangjie Wu},
title = {Rapid assembly of cyclopentene spiroisoindolinones via a rhodium-catalysed redox-neutral cascade reaction.},
journal = {Chemical Communications},
year = {2019},
volume = {55},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/C8CC08081J},
number = {2},
pages = {163--166},
doi = {10.1039/C8CC08081J}
}
Cite this
MLA
Copy
Yuan, Tingting, et al. “Rapid assembly of cyclopentene spiroisoindolinones via a rhodium-catalysed redox-neutral cascade reaction..” Chemical Communications, vol. 55, no. 2, Jan. 2019, pp. 163-166. https://doi.org/10.1039/C8CC08081J.