Rationalization of single-molecule magnet behavior in a three-coordinate Fe(iii ) complex with a high-spin state (S= 5/2)
Ning Ge
1
,
Yuan Qi Zhai
1
,
Yuan‐Qi Zhai
1
,
Yi-Fei Deng
1
,
You Song Ding
1
,
Wu Tao
1
,
Wu Tao
1
,
Zhenxing Wang
2
,
Zhong-Wen Ouyang
2
,
Hiroyuki Nojiri
3
,
Publication type: Journal Article
Publication date: 2018-08-17
scimago Q1
wos Q1
SJR: 1.276
CiteScore: 9.9
Impact factor: 6.4
ISSN: 20521545, 20521553
Inorganic Chemistry
Abstract
Here we show that in the perfect trigonal-planar geometry the iron(III) complex Fe[N(SiMe3)2]31 simultaneously has a high spin state (S = 5/2) and uniaxial magnetic anisotropy (with a zero-field splitting parameter D = −1.15(2) cm−1), as revealed by the dc SQUID magnetic susceptibility measurement, high frequency/field electron paramagnetic resonance (HF-EPR) spectroscopy and ab initio theoretical calculations. Moreover, ac magnetization data reveal a dynamic magnetic behavior with an energy barrier for magnetization reversal of 6.91(5) cm−1, and pulsed high-field magnetization shows a magnetic bistability at low-temperatures. Thus, 1 is confirmed to be a single-molecule magnet.
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Total citations:
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Citations from 2024:
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GOST
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Ge N. et al. Rationalization of single-molecule magnet behavior in a three-coordinate Fe(iii) complex with a high-spin state (S= 5/2) // Inorganic Chemistry Frontiers. 2018. Vol. 5. No. 10. pp. 2486-2492.
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Ge N., Zhai Y. Q., Zhai Y., Deng Y., Ding Y. S., Tao W., Wu Tao, Wang Z., Ouyang Z., Nojiri H., Zheng Y. Rationalization of single-molecule magnet behavior in a three-coordinate Fe(iii) complex with a high-spin state (S= 5/2) // Inorganic Chemistry Frontiers. 2018. Vol. 5. No. 10. pp. 2486-2492.
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RIS
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TY - JOUR
DO - 10.1039/C8QI00701B
UR - https://doi.org/10.1039/C8QI00701B
TI - Rationalization of single-molecule magnet behavior in a three-coordinate Fe(iii) complex with a high-spin state (S= 5/2)
T2 - Inorganic Chemistry Frontiers
AU - Ge, Ning
AU - Zhai, Yuan Qi
AU - Zhai, Yuan‐Qi
AU - Deng, Yi-Fei
AU - Ding, You Song
AU - Tao, Wu
AU - Wu Tao
AU - Wang, Zhenxing
AU - Ouyang, Zhong-Wen
AU - Nojiri, Hiroyuki
AU - Zheng, Yanzhen
PY - 2018
DA - 2018/08/17
PB - Royal Society of Chemistry (RSC)
SP - 2486-2492
IS - 10
VL - 5
SN - 2052-1545
SN - 2052-1553
ER -
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BibTex (up to 50 authors)
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@article{2018_Ge,
author = {Ning Ge and Yuan Qi Zhai and Yuan‐Qi Zhai and Yi-Fei Deng and You Song Ding and Wu Tao and Wu Tao and Zhenxing Wang and Zhong-Wen Ouyang and Hiroyuki Nojiri and Yanzhen Zheng},
title = {Rationalization of single-molecule magnet behavior in a three-coordinate Fe(iii) complex with a high-spin state (S= 5/2)},
journal = {Inorganic Chemistry Frontiers},
year = {2018},
volume = {5},
publisher = {Royal Society of Chemistry (RSC)},
month = {aug},
url = {https://doi.org/10.1039/C8QI00701B},
number = {10},
pages = {2486--2492},
doi = {10.1039/C8QI00701B}
}
Cite this
MLA
Copy
Ge, Ning, et al. “Rationalization of single-molecule magnet behavior in a three-coordinate Fe(iii) complex with a high-spin state (S= 5/2).” Inorganic Chemistry Frontiers, vol. 5, no. 10, Aug. 2018, pp. 2486-2492. https://doi.org/10.1039/C8QI00701B.
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