Synthesizing higher-capacity hard-carbons from cellulose for Na- and K-ion batteries
Hijiri Yamamoto
1
,
Shotaro Muratsubaki
1
,
Kei Kubota
1
,
Mika Fukunishi
1
,
Hiromu WATANABE
2
,
Jungmin Kim
2
,
2
Mitsubishi Chemical Corporation, Yokohama, Kanagawa 227-8502, Japan
|
Publication type: Journal Article
Publication date: 2018-08-04
scimago Q1
wos Q1
SJR: 2.462
CiteScore: 16.7
Impact factor: 9.5
ISSN: 20507488, 20507496, 09599428, 13645501
General Chemistry
General Materials Science
Renewable Energy, Sustainability and the Environment
Abstract
Non-graphitizable hard carbons are synthesized through carbonization of glucose, sucrose, maltose, cellulose, glycogen, and amylopectin. Cellulose-derived carbon delivers superior reversible sodiation capacity, and optimal carbonization for a higher capacity Na-ion battery is found to be two-step heating of cellulose at 275 °C and 1300–1500 °C in air and argon, respectively. The hard carbon delivers a higher reversible capacity of 353 mA h g−1 in a Na cell. The 275 °C heating is important to regulate dehydration and cross-linkage degrees of cellulose, which affect the nano-scale structure of hard carbons. The cellulose-derived carbons deliver 523 and 290 mA h g−1 in Li and K cells, respectively.
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182
Total citations:
182
Citations from 2024:
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(35.71%)
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Yamamoto H. et al. Synthesizing higher-capacity hard-carbons from cellulose for Na- and K-ion batteries // Journal of Materials Chemistry A. 2018. Vol. 6. No. 35. pp. 16844-16848.
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Yamamoto H., Muratsubaki S., Kubota K., Fukunishi M., WATANABE H., Kim J., Komaba S. Synthesizing higher-capacity hard-carbons from cellulose for Na- and K-ion batteries // Journal of Materials Chemistry A. 2018. Vol. 6. No. 35. pp. 16844-16848.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/C8TA05203D
UR - https://doi.org/10.1039/C8TA05203D
TI - Synthesizing higher-capacity hard-carbons from cellulose for Na- and K-ion batteries
T2 - Journal of Materials Chemistry A
AU - Yamamoto, Hijiri
AU - Muratsubaki, Shotaro
AU - Kubota, Kei
AU - Fukunishi, Mika
AU - WATANABE, Hiromu
AU - Kim, Jungmin
AU - Komaba, Shin-ichi
PY - 2018
DA - 2018/08/04
PB - Royal Society of Chemistry (RSC)
SP - 16844-16848
IS - 35
VL - 6
SN - 2050-7488
SN - 2050-7496
SN - 0959-9428
SN - 1364-5501
ER -
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BibTex (up to 50 authors)
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@article{2018_Yamamoto,
author = {Hijiri Yamamoto and Shotaro Muratsubaki and Kei Kubota and Mika Fukunishi and Hiromu WATANABE and Jungmin Kim and Shin-ichi Komaba},
title = {Synthesizing higher-capacity hard-carbons from cellulose for Na- and K-ion batteries},
journal = {Journal of Materials Chemistry A},
year = {2018},
volume = {6},
publisher = {Royal Society of Chemistry (RSC)},
month = {aug},
url = {https://doi.org/10.1039/C8TA05203D},
number = {35},
pages = {16844--16848},
doi = {10.1039/C8TA05203D}
}
Cite this
MLA
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Yamamoto, Hijiri, et al. “Synthesizing higher-capacity hard-carbons from cellulose for Na- and K-ion batteries.” Journal of Materials Chemistry A, vol. 6, no. 35, Aug. 2018, pp. 16844-16848. https://doi.org/10.1039/C8TA05203D.
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