A ‘sulfonyl-azide-free’ (SAFE) aqueous-phase diazo transfer reaction for parallel and diversity-oriented synthesis
Publication type: Journal Article
Publication date: 2019-04-08
scimago Q1
wos Q2
SJR: 1.037
CiteScore: 7.4
Impact factor: 4.2
ISSN: 13597345, 1364548X
PubMed ID:
30985842
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Abstract
Diazo transfer reactions are notoriously associated with the use of potentially explosive sulfonyl azides. The first ‘sulfonyl-azide-free’ (SAFE) protocol for producing diazo compounds from their active-methylene precursors via the Regitz diazo transfer reaction was developed and has displayed a remarkable substrate scope. It can be applied to generating arrays of diazo compounds for further evolution via combinatorial chemistry and a range of scaffold-generating transformations.
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60
Total citations:
60
Citations from 2025:
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(10%)
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MLA
Cite this
GOST
Copy
Dar’in D. et al. A ‘sulfonyl-azide-free’ (SAFE) aqueous-phase diazo transfer reaction for parallel and diversity-oriented synthesis // Chemical Communications. 2019. Vol. 55. No. 36. pp. 5239-5242.
GOST all authors (up to 50)
Copy
Dar’in D., Kantin G., Krasavin M. A ‘sulfonyl-azide-free’ (SAFE) aqueous-phase diazo transfer reaction for parallel and diversity-oriented synthesis // Chemical Communications. 2019. Vol. 55. No. 36. pp. 5239-5242.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/C9CC02042J
UR - https://xlink.rsc.org/?DOI=C9CC02042J
TI - A ‘sulfonyl-azide-free’ (SAFE) aqueous-phase diazo transfer reaction for parallel and diversity-oriented synthesis
T2 - Chemical Communications
AU - Dar’in, Dmitry
AU - Kantin, Grigory
AU - Krasavin, Mikhail
PY - 2019
DA - 2019/04/08
PB - Royal Society of Chemistry (RSC)
SP - 5239-5242
IS - 36
VL - 55
PMID - 30985842
SN - 1359-7345
SN - 1364-548X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2019_Dar’in,
author = {Dmitry Dar’in and Grigory Kantin and Mikhail Krasavin},
title = {A ‘sulfonyl-azide-free’ (SAFE) aqueous-phase diazo transfer reaction for parallel and diversity-oriented synthesis},
journal = {Chemical Communications},
year = {2019},
volume = {55},
publisher = {Royal Society of Chemistry (RSC)},
month = {apr},
url = {https://xlink.rsc.org/?DOI=C9CC02042J},
number = {36},
pages = {5239--5242},
doi = {10.1039/C9CC02042J}
}
Cite this
MLA
Copy
Dar’in, Dmitry, et al. “A ‘sulfonyl-azide-free’ (SAFE) aqueous-phase diazo transfer reaction for parallel and diversity-oriented synthesis.” Chemical Communications, vol. 55, no. 36, Apr. 2019, pp. 5239-5242. https://xlink.rsc.org/?DOI=C9CC02042J.
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