Royal Society of Chemistry (RSC)
Chemical Communications
,  volume 55 ,  issue 54 ,  pages 7760-7763

2-Iodoxybenzoic acid ditriflate: the most powerful hypervalent iodine(v) oxidant.

Mekhman S. Yusubov 1, 2, 3, 4
, 
Natalia S Soldatova 1, 2, 3, 4
, 
Pavel S Postnikov 1, 2, 3, 4
, 
Rashid R Valiev 1, 2, 3, 4, 5, 6
, 
Akira YOSHIMURA 1, 2, 3, 4, 7, 8, 9
, 
Thomas Wirth 10, 11, 12, 13, 14
, 
Victor N. Nemykin 15, 16, 17, 18, 19
, 
Viktor V Zhdankin 7, 8, 9, 20, 21
1
 
2
 
3
 
634050 Tomsk | 
4
 
Russia | 
5
 
6
 
7
 
8
 
Department of Chemistry and Biochemistry
9
 
10
 
11
 
School of chemistry
12
 
13
 
CARDIFF | 
14
 
UK | 
15
 
16
 
DEPARTMENT OF CHEMISTRY
17
 
18
 
Winnipeg | 
19
 
CANADA | 
20
 
Duluth | 
21
 
Usa | 
Publication type: Journal Article
Publication date: 2019-06-07
Royal Society of Chemistry (RSC)
scimago Q1
wos Q2
SJR: 1.037
CiteScore: 7.4
Impact factor: 4.2
ISSN: 13597345, 1364548X
DOI:  10.1039/C9CC04203B
PubMed ID:  31209449
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Abstract
A ditriflate derivative of 2-iodoxybenzoic acid (IBX) was prepared by the reaction of IBX with trifluoromethanesulfonic acid and characterized by single crystal X-ray crystallography. IBX-ditriflate is the most powerful oxidant in a series of structurally similar IBX derivatives which is best illustrated by its ability to readily oxidize hydrocarbons and the oxidation resistant polyfluoroalcohols.
Found 
Found 
6 citations
Postnikov Pavel
🥼
DSc in Chemistry
218 publications,  4 586 citations
h-index: 37
National Research Tomsk Polytechnic University
National Research Tomsk Polytechnic University
N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry of the Siberian Branch of the Russian Academy of Sciences
N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry of the Siberian Branch of the Russian Academy of Sciences
Research interests
"Smart" materials
Chemical Technology
Green chemistry
Green technologies
Hybrid materials
Metal-organic coordination polymers
Nanophotonics
Non-covalent Interactions
Organic Chemistry
Physical Chemistry
Plasmonics
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1 citation
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Research interests
Organic Chemistry
1 citation
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59 publications,  1 559 citations,  5 reviews
h-index: 24
N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences
N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences
Research interests
Organic Chemistry
1 citation
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h-index: 34
Lomonosov Moscow State University
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Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
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Volcho Konstantin
DSc in Chemistry, professor of the Russian Academy of Sciences 
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N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry of the Siberian Branch of the Russian Academy of Sciences
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1 citation
Danilkina Natalia
43 publications,  617 citations
h-index: 14
Saint Petersburg State University
Saint Petersburg State University
Research interests
Bioorganic chemistry
Click chemistry
Heterocyclic compounds
Medicinal Chemistry
Organic Chemistry
1 citation
Osipov Sergey
DSc in Chemistry
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A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
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🥼
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h-index: 14
A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences
A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences
Research interests
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Organic Chemistry
Organophosphorus chemistry
1 citation
Karasik Andrey
DSc in Chemistry, professor, associate member of the Russian Academy of Sciences 
224 publications,  2 591 citations
h-index: 26
A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences
A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences
Research interests
Coordination Chemistry
Luminescence
Phosphorus ligands
1 citation
Dotsenko Viktor
DSc in Chemistry, professor
244 publications,  2 706 citations,  2 reviews
h-index: 22
North Caucasus Federal University
North Caucasus Federal University
Kuban State University
Kuban State University
Research interests
Active methylene compounds
Biological activity
Heterocyclic compounds
Malononitrile
Selenoamides
Thioamides
1 citation
Zagidullin Almaz
🥼 🤝
PhD in Chemistry
81 publications,  876 citations
h-index: 17
A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences
A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences
Research interests
Asymmetric metal complex catalysis
Chemistry of organic and organoelement compounds; chemistry of polymers; production of materials
Coordination chemistry of phosphorus
Organoelement chemistry
Organophosphorus chemistry
Synthesis of chiral phosphorus-containing ligands
1 citation
Aksenov Aleksandr
🥼 🤝
DSc in Chemistry, professor
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h-index: 24
North Caucasus Federal University
North Caucasus Federal University
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Organic Chemistry
1 citation
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Ural Federal University
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Ilkin Vladimir
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h-index: 7
Ural Federal University
Ural Federal University
Research interests
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Heterocyclic compounds
Organic Chemistry
Synthetic Organic Chemistry
1 citation
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78 publications,  1 876 citations,  18 reviews
h-index: 25
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N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences
Research interests
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Organic electrochemistry
Organic synthesis
Photochemistry
Plant protection
1 citation
Tikhomirov Alexander
🥼 🤝
DSc in Chemistry, associate professor
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Mendeleev University of Chemical Technology of Russia
Mendeleev University of Chemical Technology of Russia
Gause Institute of New Antibiotics
Gause Institute of New Antibiotics
Research interests
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1 citation
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54 publications,  526 citations
h-index: 12
A.E. Favorsky Irkutsk Institute of Chemistry of the Siberian Branch of the Russian Academy of Sciences
A.E. Favorsky Irkutsk Institute of Chemistry of the Siberian Branch of the Russian Academy of Sciences
1 citation
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PhD in Chemistry
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h-index: 9
Ural Federal University
Ural Federal University
Research interests
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GOST Copy
Yusubov M. S. et al. 2-Iodoxybenzoic acid ditriflate: the most powerful hypervalent iodine(v) oxidant. // Chemical Communications. 2019. Vol. 55. No. 54. pp. 7760-7763.
GOST all authors (up to 50) Copy
Yusubov M. S., Soldatova N. S., Postnikov P. S., Valiev R. R., YOSHIMURA A., Wirth T., Nemykin V. N., Zhdankin V. V. 2-Iodoxybenzoic acid ditriflate: the most powerful hypervalent iodine(v) oxidant. // Chemical Communications. 2019. Vol. 55. No. 54. pp. 7760-7763.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1039/C9CC04203B
UR - https://xlink.rsc.org/?DOI=C9CC04203B
TI - 2-Iodoxybenzoic acid ditriflate: the most powerful hypervalent iodine(v) oxidant.
T2 - Chemical Communications
AU - Yusubov, Mekhman S.
AU - Soldatova, Natalia S
AU - Postnikov, Pavel S
AU - Valiev, Rashid R
AU - YOSHIMURA, Akira
AU - Wirth, Thomas
AU - Nemykin, Victor N.
AU - Zhdankin, Viktor V
PY - 2019
DA - 2019/06/07
PB - Royal Society of Chemistry (RSC)
SP - 7760-7763
IS - 54
VL - 55
PMID - 31209449
SN - 1359-7345
SN - 1364-548X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2019_Yusubov,
author = {Mekhman S. Yusubov and Natalia S Soldatova and Pavel S Postnikov and Rashid R Valiev and Akira YOSHIMURA and Thomas Wirth and Victor N. Nemykin and Viktor V Zhdankin},
title = {2-Iodoxybenzoic acid ditriflate: the most powerful hypervalent iodine(v) oxidant.},
journal = {Chemical Communications},
year = {2019},
volume = {55},
publisher = {Royal Society of Chemistry (RSC)},
month = {jun},
url = {https://xlink.rsc.org/?DOI=C9CC04203B},
number = {54},
pages = {7760--7763},
doi = {10.1039/C9CC04203B}
}
MLA
Cite this
MLA Copy
Yusubov, Mekhman S., et al. “2-Iodoxybenzoic acid ditriflate: the most powerful hypervalent iodine(v) oxidant..” Chemical Communications, vol. 55, no. 54, Jun. 2019, pp. 7760-7763. https://xlink.rsc.org/?DOI=C9CC04203B.