Bis(2,1,3-benzotelluradiazolidyl)2,1,3-benzotelluradiazole: a pair of radical anions coupled by Te⋯N chalcogen bonding
Nikolay A. Pushkarevsky
1, 2, 3, 4, 5, 6, 7
,
Anton I. Smolentsev
1, 2
,
Alexey Dmitriev
4, 5, 6, 8, 9, 10, 11
,
Ignacio Vargas-Baca
12, 13, 14, 15, 16
,
N.P Gritsan
4, 5, 6, 8, 9, 10, 11
,
Jens Beckmann
17, 18, 19, 20, 21
,
Andrey V. Zibarev
5, 6, 9, 11, 22, 23, 24
4
Siberian branch of the Russian Academy of sciences
5
630090 Novosibirsk
|
6
Russia
|
7
Department of Natural Sciences
11
Department of Physics
13
Department of Chemistry and Chemical Biology
15
Hamilton
16
CANADA
|
17
18
Institute for Inorganic Chemistry and Crystallography
20
28359 Bremen
|
21
GERMANY
|
Publication type: Journal Article
Publication date: 2020-01-01
scimago Q1
wos Q2
SJR: 1.037
CiteScore: 7.4
Impact factor: 4.2
ISSN: 13597345, 1364548X
PubMed ID:
31894772
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Abstract
Reduction of 2,1,3-benzotelluradiazole (3) yielded a crystalline solid that features a trimeric dianion formally composed of two [3]˙− and one 3 bridged by unusually asymmetric Te⋯N chalcogen bonds. The solid is diamagnetic due to strong antiferromagnetic coupling, as revealed by CASSCF/CASPT2 and BS-DFT.
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22
Total citations:
22
Citations from 2025:
2
(9.09%)
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Pushkarevsky N. A. et al. Bis(2,1,3-benzotelluradiazolidyl)2,1,3-benzotelluradiazole: a pair of radical anions coupled by Te⋯N chalcogen bonding // Chemical Communications. 2020. Vol. 56. No. 7. pp. 1113-1116.
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Pushkarevsky N. A., Smolentsev A. I., Dmitriev A., Vargas-Baca I., Gritsan N., Beckmann J., Zibarev A. V. Bis(2,1,3-benzotelluradiazolidyl)2,1,3-benzotelluradiazole: a pair of radical anions coupled by Te⋯N chalcogen bonding // Chemical Communications. 2020. Vol. 56. No. 7. pp. 1113-1116.
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RIS
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TY - JOUR
DO - 10.1039/C9CC08110K
UR - https://xlink.rsc.org/?DOI=C9CC08110K
TI - Bis(2,1,3-benzotelluradiazolidyl)2,1,3-benzotelluradiazole: a pair of radical anions coupled by Te⋯N chalcogen bonding
T2 - Chemical Communications
AU - Pushkarevsky, Nikolay A.
AU - Smolentsev, Anton I.
AU - Dmitriev, Alexey
AU - Vargas-Baca, Ignacio
AU - Gritsan, N.P
AU - Beckmann, Jens
AU - Zibarev, Andrey V.
PY - 2020
DA - 2020/01/01
PB - Royal Society of Chemistry (RSC)
SP - 1113-1116
IS - 7
VL - 56
PMID - 31894772
SN - 1359-7345
SN - 1364-548X
ER -
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BibTex (up to 50 authors)
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@article{2020_Pushkarevsky,
author = {Nikolay A. Pushkarevsky and Anton I. Smolentsev and Alexey Dmitriev and Ignacio Vargas-Baca and N.P Gritsan and Jens Beckmann and Andrey V. Zibarev},
title = {Bis(2,1,3-benzotelluradiazolidyl)2,1,3-benzotelluradiazole: a pair of radical anions coupled by Te⋯N chalcogen bonding},
journal = {Chemical Communications},
year = {2020},
volume = {56},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://xlink.rsc.org/?DOI=C9CC08110K},
number = {7},
pages = {1113--1116},
doi = {10.1039/C9CC08110K}
}
Cite this
MLA
Copy
Pushkarevsky, Nikolay A., et al. “Bis(2,1,3-benzotelluradiazolidyl)2,1,3-benzotelluradiazole: a pair of radical anions coupled by Te⋯N chalcogen bonding.” Chemical Communications, vol. 56, no. 7, Jan. 2020, pp. 1113-1116. https://xlink.rsc.org/?DOI=C9CC08110K.