A catalyst-free bis(triflyl)ethylation/benzannulation reaction: rapid access to carbazole-based superacidic carbon acids from alkynols
Irene Martín Mejías
1
,
Irene Martín-Mejías
1, 2, 3, 4, 5
,
Cristina Aragoncillo
6, 7, 8, 9, 10, 11
,
Hikaru Yanai
12, 13, 14, 15, 16
,
Shoki Hoshikawa
12, 13, 14, 15, 16
,
Yuuki FUJIMOTO
12, 13, 14, 15, 16
,
TAKASHI MATSUMOTO
12
,
Pedro Almendros
1, 2, 3, 4, 5
3
IQOG-CSIC
4
28006-Madrid
|
5
SPAIN
|
7
Grupo de Lactamas y Heterociclos Bioactivos
8
Departamento de Química Orgánica
9
Unidad Asociada al CSIC
10
Facultad de Química
13
School of Pharmacy
15
Hachioji
|
16
JAPAN
|
Publication type: Journal Article
Publication date: 2020-01-03
scimago Q1
wos Q2
SJR: 1.037
CiteScore: 7.4
Impact factor: 4.2
ISSN: 13597345, 1364548X
PubMed ID:
31950123
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Abstract
Carbazoles possessing Tf2CHCH2 groups were obtained by the reaction of 1-(indol-2-yl)but-3-yn-1-ols with in situ-generated Tf2CCH2 through vicinal difunctionalisation of the alkyne moiety, where the vinyl-type carbocation intermediate was selectively attacked by the indole moiety and not by the carbanion moiety.
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Metrics
14
Total citations:
14
Citations from 2024:
5
(35.71%)
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GOST
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Martín Mejías I. et al. A catalyst-free bis(triflyl)ethylation/benzannulation reaction: rapid access to carbazole-based superacidic carbon acids from alkynols // Chemical Communications. 2020. Vol. 56. No. 12. pp. 1795-1798.
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Martín Mejías I., Martín-Mejías I., Aragoncillo C., Yanai H., Hoshikawa S., FUJIMOTO Y., MATSUMOTO T., Almendros P. A catalyst-free bis(triflyl)ethylation/benzannulation reaction: rapid access to carbazole-based superacidic carbon acids from alkynols // Chemical Communications. 2020. Vol. 56. No. 12. pp. 1795-1798.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/c9cc08930f
UR - https://xlink.rsc.org/?DOI=C9CC08930F
TI - A catalyst-free bis(triflyl)ethylation/benzannulation reaction: rapid access to carbazole-based superacidic carbon acids from alkynols
T2 - Chemical Communications
AU - Martín Mejías, Irene
AU - Martín-Mejías, Irene
AU - Aragoncillo, Cristina
AU - Yanai, Hikaru
AU - Hoshikawa, Shoki
AU - FUJIMOTO, Yuuki
AU - MATSUMOTO, TAKASHI
AU - Almendros, Pedro
PY - 2020
DA - 2020/01/03
PB - Royal Society of Chemistry (RSC)
SP - 1795-1798
IS - 12
VL - 56
PMID - 31950123
SN - 1359-7345
SN - 1364-548X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2020_Martín Mejías,
author = {Irene Martín Mejías and Irene Martín-Mejías and Cristina Aragoncillo and Hikaru Yanai and Shoki Hoshikawa and Yuuki FUJIMOTO and TAKASHI MATSUMOTO and Pedro Almendros},
title = {A catalyst-free bis(triflyl)ethylation/benzannulation reaction: rapid access to carbazole-based superacidic carbon acids from alkynols},
journal = {Chemical Communications},
year = {2020},
volume = {56},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://xlink.rsc.org/?DOI=C9CC08930F},
number = {12},
pages = {1795--1798},
doi = {10.1039/c9cc08930f}
}
Cite this
MLA
Copy
Martín Mejías, Irene, et al. “A catalyst-free bis(triflyl)ethylation/benzannulation reaction: rapid access to carbazole-based superacidic carbon acids from alkynols.” Chemical Communications, vol. 56, no. 12, Jan. 2020, pp. 1795-1798. https://xlink.rsc.org/?DOI=C9CC08930F.