Structural diversity of zinc(ii) coordination polymers with octafluorobiphenyl-4,4′-dicarboxylate based on mononuclear, paddle wheel and cuboidal units
Anastasia M Cheplakova
1, 2, 3, 4, 5, 6
,
Konstantin A. Kovalenko
1, 2, 3, 4, 5, 6
,
Denis G. Samsonenko
1, 2, 3, 4, 5, 6
,
Andrey S Vinogradov
4, 5, 7, 8
,
Victor M Karpov
4, 5, 7, 8
,
Vyacheslav E Platonov
4, 5, 7, 8
,
Vladimir P. Fedin
1, 2, 3, 4, 5, 6
4
Novosibirsk
|
5
RUSSIAN FEDERATION
|
Publication type: Journal Article
Publication date: 2019-02-22
scimago Q2
wos Q2
SJR: 0.520
CiteScore: 5.2
Impact factor: 2.6
ISSN: 14668033
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
We present a series of six novel Zn(II) complexes containing anions of perfluorinated biphenyl-4,4′-dicarboxylate (oFBPDC2−). Among them are the 0D complex [Zn(eg)3](oFBPDC) (eg = ethylene glycol), the 1D [Zn(H2O)(ur)(oFBPDC)] (ur = urotropine) and [Zn(CH3OH)2(CH3OCH2CH2OH)(oFBPDC)] and the 2D layered [Zn2(CH3CN)2(oFBPDC)2]·2C6H6·2CH3CN, [Zn2(H2O)2(oFBPDC)2]·4(CH3)2CO, [{Zn4(μ3-OCH3)4}(CH3OH)4(oFBPDC)2]·[{Zn4(μ3-OCH3)4}(H2O)(CH3OH)3(oFBPDC)2]·13CH3OH. The latter coordination polymer is built up by unique Zn4(OCH3)4 cuboidal units. The complexes are characterized by single-crystal X-ray diffraction, FT-IR, elemental analysis, and TGA. Investigation of the CO2 adsorption at 195 K on [Zn2(CH3CN)2(oFBPDC)2] and [Zn2(H2O)2(oFBPDC)2] of the layered polymeric structure revealed that they have BET surface areas of 334.8 and 150.6 m2 g−1, respectively.
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Cheplakova A. M. et al. Structural diversity of zinc(ii) coordination polymers with octafluorobiphenyl-4,4′-dicarboxylate based on mononuclear, paddle wheel and cuboidal units // CrystEngComm. 2019. Vol. 21. No. 15. pp. 2524-2533.
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Cheplakova A. M., Kovalenko K. A., Samsonenko D. G., Vinogradov A. S., Karpov V. M., Platonov V. E., Fedin V. P. Structural diversity of zinc(ii) coordination polymers with octafluorobiphenyl-4,4′-dicarboxylate based on mononuclear, paddle wheel and cuboidal units // CrystEngComm. 2019. Vol. 21. No. 15. pp. 2524-2533.
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TY - JOUR
DO - 10.1039/C9CE00073A
UR - https://xlink.rsc.org/?DOI=C9CE00073A
TI - Structural diversity of zinc(ii) coordination polymers with octafluorobiphenyl-4,4′-dicarboxylate based on mononuclear, paddle wheel and cuboidal units
T2 - CrystEngComm
AU - Cheplakova, Anastasia M
AU - Kovalenko, Konstantin A.
AU - Samsonenko, Denis G.
AU - Vinogradov, Andrey S
AU - Karpov, Victor M
AU - Platonov, Vyacheslav E
AU - Fedin, Vladimir P.
PY - 2019
DA - 2019/02/22
PB - Royal Society of Chemistry (RSC)
SP - 2524-2533
IS - 15
VL - 21
SN - 1466-8033
ER -
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@article{2019_Cheplakova,
author = {Anastasia M Cheplakova and Konstantin A. Kovalenko and Denis G. Samsonenko and Andrey S Vinogradov and Victor M Karpov and Vyacheslav E Platonov and Vladimir P. Fedin},
title = {Structural diversity of zinc(ii) coordination polymers with octafluorobiphenyl-4,4′-dicarboxylate based on mononuclear, paddle wheel and cuboidal units},
journal = {CrystEngComm},
year = {2019},
volume = {21},
publisher = {Royal Society of Chemistry (RSC)},
month = {feb},
url = {https://xlink.rsc.org/?DOI=C9CE00073A},
number = {15},
pages = {2524--2533},
doi = {10.1039/C9CE00073A}
}
Cite this
MLA
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Cheplakova, Anastasia M., et al. “Structural diversity of zinc(ii) coordination polymers with octafluorobiphenyl-4,4′-dicarboxylate based on mononuclear, paddle wheel and cuboidal units.” CrystEngComm, vol. 21, no. 15, Feb. 2019, pp. 2524-2533. https://xlink.rsc.org/?DOI=C9CE00073A.