Physical Chemistry Chemical Physics

, том 21 , издание 43 , страницы 24232-24238

Defect formation and migration in Nasicon Li_1+xAl_xTi_2−x(PO₄)₃

Тип публикации: Journal Article

Дата публикации: 2019-10-23

Royal Society of Chemistry (RSC)

Physical Chemistry Chemical Physics

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SJR: 0.698

CiteScore: 5.3

Impact factor: 2.9

ISSN: 14639076, 14639084

DOI: 10.1039/c9cp04792a

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PubMed ID: 31661096

Physical and Theoretical Chemistry

General Physics and Astronomy

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NASICON-structured materials of the composition Li1+xAlxTi2−x(PO4)3 are regarded as solid electrolytes with high Li-ion conductivity applicable in all solid-state batteries. In this study we investigate the migration paths of constituting ions and monovalent charge carriers including K+, Na+, and, H+. The results proof that Li is the most mobile species in the investigated composition and that the formation of intrinsic defects is unlikely. In addition, we find surprisingly low migration energy for oxygen vacancies in the structure of the dedicated Li-ion conductor.

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Arjmandi H. R. et al. Defect formation and migration in Nasicon Li1+xAlxTi2−x(PO4)3 // Physical Chemistry Chemical Physics. 2019. Vol. 21. No. 43. pp. 24232-24238.

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Arjmandi H. R., Grieshammer S. Defect formation and migration in Nasicon Li1+xAlxTi2−x(PO4)3 // Physical Chemistry Chemical Physics. 2019. Vol. 21. No. 43. pp. 24232-24238.

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TY - JOUR

DO - 10.1039/c9cp04792a

UR - https://xlink.rsc.org/?DOI=C9CP04792A

TI - Defect formation and migration in Nasicon Li1+xAlxTi2−x(PO4)3

T2 - Physical Chemistry Chemical Physics

AU - Arjmandi, Hamid R

AU - Grieshammer, Steffen

PY - 2019

DA - 2019/10/23

PB - Royal Society of Chemistry (RSC)

SP - 24232-24238

IS - 43

VL - 21

PMID - 31661096

SN - 1463-9076

SN - 1463-9084

ER -

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@article{2019_Arjmandi,

author = {Hamid R Arjmandi and Steffen Grieshammer},

title = {Defect formation and migration in Nasicon Li1+xAlxTi2−x(PO4)3},

journal = {Physical Chemistry Chemical Physics},

year = {2019},

volume = {21},

publisher = {Royal Society of Chemistry (RSC)},

month = {oct},

url = {https://xlink.rsc.org/?DOI=C9CP04792A},

number = {43},

pages = {24232--24238},

doi = {10.1039/c9cp04792a}

}

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Arjmandi, Hamid R., et al. “Defect formation and migration in Nasicon Li1+xAlxTi2−x(PO4)3.” Physical Chemistry Chemical Physics, vol. 21, no. 43, Oct. 2019, pp. 24232-24238. https://xlink.rsc.org/?DOI=C9CP04792A.