Royal Society of Chemistry (RSC)
Physical Chemistry Chemical Physics
,  volume 21 ,  issue 43 ,  pages 24232-24238

Defect formation and migration in Nasicon Li1+xAlxTi2−x(PO4)3

Publication type: Journal Article
Publication date: 2019-10-23
Royal Society of Chemistry (RSC)
scimago Q2
wos Q2
SJR: 0.698
CiteScore: 5.3
Impact factor: 2.9
ISSN: 14639076, 14639084
DOI:  10.1039/c9cp04792a
PubMed ID:  31661096
Physical and Theoretical Chemistry
General Physics and Astronomy
Abstract
NASICON-structured materials of the composition Li1+xAlxTi2−x(PO4)3 are regarded as solid electrolytes with high Li-ion conductivity applicable in all solid-state batteries. In this study we investigate the migration paths of constituting ions and monovalent charge carriers including K+, Na+, and, H+. The results proof that Li is the most mobile species in the investigated composition and that the formation of intrinsic defects is unlikely. In addition, we find surprisingly low migration energy for oxygen vacancies in the structure of the dedicated Li-ion conductor.
Found 
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GOST |
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GOST Copy
Arjmandi H. R. et al. Defect formation and migration in Nasicon Li1+xAlxTi2−x(PO4)3 // Physical Chemistry Chemical Physics. 2019. Vol. 21. No. 43. pp. 24232-24238.
GOST all authors (up to 50) Copy
Arjmandi H. R., Grieshammer S. Defect formation and migration in Nasicon Li1+xAlxTi2−x(PO4)3 // Physical Chemistry Chemical Physics. 2019. Vol. 21. No. 43. pp. 24232-24238.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1039/c9cp04792a
UR - https://xlink.rsc.org/?DOI=C9CP04792A
TI - Defect formation and migration in Nasicon Li1+xAlxTi2−x(PO4)3
T2 - Physical Chemistry Chemical Physics
AU - Arjmandi, Hamid R
AU - Grieshammer, Steffen
PY - 2019
DA - 2019/10/23
PB - Royal Society of Chemistry (RSC)
SP - 24232-24238
IS - 43
VL - 21
PMID - 31661096
SN - 1463-9076
SN - 1463-9084
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2019_Arjmandi,
author = {Hamid R Arjmandi and Steffen Grieshammer},
title = {Defect formation and migration in Nasicon Li1+xAlxTi2−x(PO4)3},
journal = {Physical Chemistry Chemical Physics},
year = {2019},
volume = {21},
publisher = {Royal Society of Chemistry (RSC)},
month = {oct},
url = {https://xlink.rsc.org/?DOI=C9CP04792A},
number = {43},
pages = {24232--24238},
doi = {10.1039/c9cp04792a}
}
MLA
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MLA Copy
Arjmandi, Hamid R., et al. “Defect formation and migration in Nasicon Li1+xAlxTi2−x(PO4)3.” Physical Chemistry Chemical Physics, vol. 21, no. 43, Oct. 2019, pp. 24232-24238. https://xlink.rsc.org/?DOI=C9CP04792A.