TbO+ in a calcium apatite matrix featuring a triple trigger-type relaxation of magnetization.
P. E. Kazin
1, 2, 3, 4, 5
,
Mikhail A Zykin
3, 4, 5, 6, 7
,
Oxana Magdysyuk
8
,
Oxana V. Magdysyuk
9, 10, 11
,
Valentina Utochnikova
1, 2, 3, 4, 5
,
Reinhard K. Kremer
12
,
Walter Schnelle
13, 14, 15, 16
,
Claudia Felser
13
,
Martin Jansen
12, 13, 14, 15, 16, 17, 18
2
DEPARTMENT OF CHEMISTRY
4
119991 Moscow
5
Russia
|
7
Department of Materials Science
10
OX11 0DE Didcot
|
11
UK
|
13
15
01187 Dresden
|
16
GERMANY
|
18
70569 Stuttgart
Publication type: Journal Article
Publication date: 2019-03-26
scimago Q2
wos Q1
SJR: 0.653
CiteScore: 6.0
Impact factor: 3.3
ISSN: 14779226, 14779234
PubMed ID:
30933206
Inorganic Chemistry
Abstract
Tb for Ca substituted hydroxyapatite ceramic samples with composition Ca10-xTbx(PO4)6(OH1-x/2-δ)2, where x = 0.1, 0.5, were synthesized by solid-state reaction at 1300 °C in air, and their crystal structure, vibrational spectra, luminescence, and magnetic properties were studied. Implanting Tb3+ into the calcium apatite crystal lattice results in formation of an effective TbO+ ion which displays a short terbium-oxygen bond of 2.15 Å and a stretching vibration at 534 cm-1. The Tb3+ electronic structure has been revealed by analyzing the luminescence spectra and dc/ac magnetization data. Accordingly, the ground state represents a pseudo doublet with MJ = ±6 and the first exited level is by 112 cm-1 higher in energy. The ion exhibits field induced magnetic bistability with the magnetization reversing over the first exited state. Three paths of magnetization relaxation with field-temperature controlled switching between the paths have been identified.
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Total citations:
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Citations from 2024:
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(16.66%)
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Kazin P. E. et al. TbO+ in a calcium apatite matrix featuring a triple trigger-type relaxation of magnetization. // Dalton Transactions. 2019. Vol. 48. No. 16. pp. 5299-5307.
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Kazin P. E., Zykin M. A., Magdysyuk O., Magdysyuk O. V., Utochnikova V., Gorbachev E. A., Kremer R. K., Schnelle W., Felser C., Jansen M. TbO+ in a calcium apatite matrix featuring a triple trigger-type relaxation of magnetization. // Dalton Transactions. 2019. Vol. 48. No. 16. pp. 5299-5307.
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TY - JOUR
DO - 10.1039/C9DT01120J
UR - https://xlink.rsc.org/?DOI=C9DT01120J
TI - TbO+ in a calcium apatite matrix featuring a triple trigger-type relaxation of magnetization.
T2 - Dalton Transactions
AU - Kazin, P. E.
AU - Zykin, Mikhail A
AU - Magdysyuk, Oxana
AU - Magdysyuk, Oxana V.
AU - Utochnikova, Valentina
AU - Gorbachev, Evgeny A
AU - Kremer, Reinhard K.
AU - Schnelle, Walter
AU - Felser, Claudia
AU - Jansen, Martin
PY - 2019
DA - 2019/03/26
PB - Royal Society of Chemistry (RSC)
SP - 5299-5307
IS - 16
VL - 48
PMID - 30933206
SN - 1477-9226
SN - 1477-9234
ER -
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BibTex (up to 50 authors)
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@article{2019_Kazin,
author = {P. E. Kazin and Mikhail A Zykin and Oxana Magdysyuk and Oxana V. Magdysyuk and Valentina Utochnikova and Evgeny A Gorbachev and Reinhard K. Kremer and Walter Schnelle and Claudia Felser and Martin Jansen},
title = {TbO+ in a calcium apatite matrix featuring a triple trigger-type relaxation of magnetization.},
journal = {Dalton Transactions},
year = {2019},
volume = {48},
publisher = {Royal Society of Chemistry (RSC)},
month = {mar},
url = {https://xlink.rsc.org/?DOI=C9DT01120J},
number = {16},
pages = {5299--5307},
doi = {10.1039/C9DT01120J}
}
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MLA
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Kazin, P. E., et al. “TbO+ in a calcium apatite matrix featuring a triple trigger-type relaxation of magnetization..” Dalton Transactions, vol. 48, no. 16, Mar. 2019, pp. 5299-5307. https://xlink.rsc.org/?DOI=C9DT01120J.