volume 48 issue 22 pages 7677-7684

Energetic furazan-triazole hybrid with dinitromethyl and nitramino groups: decreasing sensitivity via the formation of a planar anion

Yongxing Tang, 1, 2, 3, 4
Chunlin He 1, 2, 3, 4, 5
Gregory H Imler 4, 6, 7
Damon A. Parrish 4, 6, 7
Jean'ne M. Shreeve 1, 2, 3, 4
1
 
DEPARTMENT OF CHEMISTRY
3
 
Moscow
4
 
Usa
5
 
School of Materials Science & Engineering
6
 
NAVAL RESEARCH LABORATORY
7
 
WASHINGTON
Publication typeJournal Article
Publication date2019-04-30
scimago Q2
wos Q1
SJR0.653
CiteScore6.0
Impact factor3.3
ISSN14779226, 14779234
PubMed ID:  31062806
Inorganic Chemistry
Abstract
Energetic salts (4, 5 and 7–11) of 3-(3-dinitromethanide-1H-1,2,4-triazol-5-yl)-4-nitraminofurazanate and the azo compound (15) as well as its ammonium (14), hydrazinium (16) and hydroxylammonium (17) salts were synthesized and fully characterized. The structures of 5 and 15 were confirmed by single crystal X-ray diffraction analysis. The hydroxylammonium salt (5) has a high measured density (1.85 g cm−3) and shows promising properties as a replacement for the traditional explosive (RDX). The anion is planar which suggests that a combination of two heterocyclic five-membered rings with nitramino and dinitromethyl groups could open a new avenue to advanced energetic materials with high detonation performance and good sensitivities.
Found 
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Tang, Y. et al. Energetic furazan-triazole hybrid with dinitromethyl and nitramino groups: decreasing sensitivity via the formation of a planar anion // Dalton Transactions. 2019. Vol. 48. No. 22. pp. 7677-7684.
GOST all authors (up to 50) Copy
Tang, Y., He C., Imler G. H., Parrish D. A., Shreeve J. M. Energetic furazan-triazole hybrid with dinitromethyl and nitramino groups: decreasing sensitivity via the formation of a planar anion // Dalton Transactions. 2019. Vol. 48. No. 22. pp. 7677-7684.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1039/C9DT01514K
UR - https://xlink.rsc.org/?DOI=C9DT01514K
TI - Energetic furazan-triazole hybrid with dinitromethyl and nitramino groups: decreasing sensitivity via the formation of a planar anion
T2 - Dalton Transactions
AU - Tang,, Yongxing
AU - He, Chunlin
AU - Imler, Gregory H
AU - Parrish, Damon A.
AU - Shreeve, Jean'ne M.
PY - 2019
DA - 2019/04/30
PB - Royal Society of Chemistry (RSC)
SP - 7677-7684
IS - 22
VL - 48
PMID - 31062806
SN - 1477-9226
SN - 1477-9234
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2019_Tang,,
author = {Yongxing Tang, and Chunlin He and Gregory H Imler and Damon A. Parrish and Jean'ne M. Shreeve},
title = {Energetic furazan-triazole hybrid with dinitromethyl and nitramino groups: decreasing sensitivity via the formation of a planar anion},
journal = {Dalton Transactions},
year = {2019},
volume = {48},
publisher = {Royal Society of Chemistry (RSC)},
month = {apr},
url = {https://xlink.rsc.org/?DOI=C9DT01514K},
number = {22},
pages = {7677--7684},
doi = {10.1039/C9DT01514K}
}
MLA
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MLA Copy
Tang,, Yongxing, et al. “Energetic furazan-triazole hybrid with dinitromethyl and nitramino groups: decreasing sensitivity via the formation of a planar anion.” Dalton Transactions, vol. 48, no. 22, Apr. 2019, pp. 7677-7684. https://xlink.rsc.org/?DOI=C9DT01514K.