Energetic furazan-triazole hybrid with dinitromethyl and nitramino groups: decreasing sensitivity via the formation of a planar anion
Тип публикации: Journal Article
Дата публикации: 2019-04-30
SCImago Q2
WOS Q1
БС1
SJR: 0.581
CiteScore: 6
Impact factor: 3.3
ISSN: 14779226, 14779234
PubMed ID:
31062806
Inorganic Chemistry
Краткое описание
Energetic salts (4, 5 and 7–11) of 3-(3-dinitromethanide-1H-1,2,4-triazol-5-yl)-4-nitraminofurazanate and the azo compound (15) as well as its ammonium (14), hydrazinium (16) and hydroxylammonium (17) salts were synthesized and fully characterized. The structures of 5 and 15 were confirmed by single crystal X-ray diffraction analysis. The hydroxylammonium salt (5) has a high measured density (1.85 g cm−3) and shows promising properties as a replacement for the traditional explosive (RDX). The anion is planar which suggests that a combination of two heterocyclic five-membered rings with nitramino and dinitromethyl groups could open a new avenue to advanced energetic materials with high detonation performance and good sensitivities.
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Tang, Y. et al. Energetic furazan-triazole hybrid with dinitromethyl and nitramino groups: decreasing sensitivity via the formation of a planar anion // Dalton Transactions. 2019. Vol. 48. No. 22. pp. 7677-7684.
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Tang, Y., He C., Imler G. H., Parrish D. A., Shreeve J. M. Energetic furazan-triazole hybrid with dinitromethyl and nitramino groups: decreasing sensitivity via the formation of a planar anion // Dalton Transactions. 2019. Vol. 48. No. 22. pp. 7677-7684.
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TY - JOUR
DO - 10.1039/C9DT01514K
UR - https://xlink.rsc.org/?DOI=C9DT01514K
TI - Energetic furazan-triazole hybrid with dinitromethyl and nitramino groups: decreasing sensitivity via the formation of a planar anion
T2 - Dalton Transactions
AU - Tang,, Yongxing
AU - He, Chunlin
AU - Imler, Gregory H
AU - Parrish, Damon A.
AU - Shreeve, Jean'ne M.
PY - 2019
DA - 2019/04/30
PB - Royal Society of Chemistry (RSC)
SP - 7677-7684
IS - 22
VL - 48
PMID - 31062806
SN - 1477-9226
SN - 1477-9234
ER -
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@article{2019_Tang,,
author = {Yongxing Tang, and Chunlin He and Gregory H Imler and Damon A. Parrish and Jean'ne M. Shreeve},
title = {Energetic furazan-triazole hybrid with dinitromethyl and nitramino groups: decreasing sensitivity via the formation of a planar anion},
journal = {Dalton Transactions},
year = {2019},
volume = {48},
publisher = {Royal Society of Chemistry (RSC)},
month = {apr},
url = {https://xlink.rsc.org/?DOI=C9DT01514K},
number = {22},
pages = {7677--7684},
doi = {10.1039/C9DT01514K}
}
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Tang,, Yongxing, et al. “Energetic furazan-triazole hybrid with dinitromethyl and nitramino groups: decreasing sensitivity via the formation of a planar anion.” Dalton Transactions, vol. 48, no. 22, Apr. 2019, pp. 7677-7684. https://xlink.rsc.org/?DOI=C9DT01514K.
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