N-Thiocyanato-dibenzenesulfonimide: a new electrophilic thiocyanating reagent with enhanced reactivity.
Chengqiu LI
1, 2, 3, 4, 5
,
Pingliang Long
1, 2, 3, 4, 5
,
Haopeng Wu
1
,
Hongquan Yin
1
,
Fuxue Chen
1, 2, 3, 4, 5
2
School of Chemistry & Chemical Engineering
4
Beijing 102488
|
5
CHINA
|
Publication type: Journal Article
Publication date: 2019-07-05
scimago Q2
wos Q2
SJR: 0.600
CiteScore: 5.2
Impact factor: 2.7
ISSN: 14770520, 14770539
PubMed ID:
31309967
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
A novel electrophilic thiocyanating reagent, N-thiocyanato-dibenzenesulfonimide, was prepared and exhibited enhanced electrophilicity with a wide scope of substrates. Thus, it reacted with activated aromatics such as phenols, indoles, anilines and anisoles without a catalyst giving the corresponding thicyanate derivatives in high yields, while TfOH for unactivated arenes and hetero aromatics and Zn(OTf)2 for ketones was used as the catalyst, respectively. It is noteworthy that internal alkenes and styrenes were bifunctionalized giving 1,2-amino thiocyanates in high yields.
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56
Total citations:
56
Citations from 2025:
9
(16.07%)
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GOST
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LI C. et al. N-Thiocyanato-dibenzenesulfonimide: a new electrophilic thiocyanating reagent with enhanced reactivity. // Organic and Biomolecular Chemistry. 2019. Vol. 17. No. 30. pp. 7131-7134.
GOST all authors (up to 50)
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LI C., Long P., Wu H., Yin H., Chen F. N-Thiocyanato-dibenzenesulfonimide: a new electrophilic thiocyanating reagent with enhanced reactivity. // Organic and Biomolecular Chemistry. 2019. Vol. 17. No. 30. pp. 7131-7134.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/C9OB01340G
UR - https://xlink.rsc.org/?DOI=C9OB01340G
TI - N-Thiocyanato-dibenzenesulfonimide: a new electrophilic thiocyanating reagent with enhanced reactivity.
T2 - Organic and Biomolecular Chemistry
AU - LI, Chengqiu
AU - Long, Pingliang
AU - Wu, Haopeng
AU - Yin, Hongquan
AU - Chen, Fuxue
PY - 2019
DA - 2019/07/05
PB - Royal Society of Chemistry (RSC)
SP - 7131-7134
IS - 30
VL - 17
PMID - 31309967
SN - 1477-0520
SN - 1477-0539
ER -
Cite this
BibTex (up to 50 authors)
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@article{2019_LI,
author = {Chengqiu LI and Pingliang Long and Haopeng Wu and Hongquan Yin and Fuxue Chen},
title = {N-Thiocyanato-dibenzenesulfonimide: a new electrophilic thiocyanating reagent with enhanced reactivity.},
journal = {Organic and Biomolecular Chemistry},
year = {2019},
volume = {17},
publisher = {Royal Society of Chemistry (RSC)},
month = {jul},
url = {https://xlink.rsc.org/?DOI=C9OB01340G},
number = {30},
pages = {7131--7134},
doi = {10.1039/C9OB01340G}
}
Cite this
MLA
Copy
LI, Chengqiu, et al. “N-Thiocyanato-dibenzenesulfonimide: a new electrophilic thiocyanating reagent with enhanced reactivity..” Organic and Biomolecular Chemistry, vol. 17, no. 30, Jul. 2019, pp. 7131-7134. https://xlink.rsc.org/?DOI=C9OB01340G.