Cascade cyclization reactions of alkylidenecyclopropanes for the construction of polycyclic lactams and lactones by visible light photoredox catalysis
2
State Key Laboratory of Organometallic Chemistry
3
Center for Excellence in Molecular Synthesis
6
Chinese Academy of sciences
Publication type: Journal Article
Publication date: 2020-01-01
scimago Q1
wos Q1
SJR: 1.068
CiteScore: 8.2
Impact factor: 4.7
ISSN: 20524110, 20524129
Organic Chemistry
Abstract
A visible light photocatalytic cascade cyclization reaction of alkylidenecyclopropanes for the rapid construction of seven- and eight-membered ring-containing polycyclic lactams and lactones has been developed. The process is proposed to proceed through a radical pathway, and the suggested radical intermediate was captured by TEMPO successfully. An intermolecular version of the reaction was also achieved, affording a variety of methyl dialinoacetate products.
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Total citations:
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Citations from 2024:
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Chen M. et al. Cascade cyclization reactions of alkylidenecyclopropanes for the construction of polycyclic lactams and lactones by visible light photoredox catalysis // Organic Chemistry Frontiers. 2020. Vol. 7. No. 2. pp. 374-379.
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Chen M., Wei Yin 尹., Shi M. Cascade cyclization reactions of alkylidenecyclopropanes for the construction of polycyclic lactams and lactones by visible light photoredox catalysis // Organic Chemistry Frontiers. 2020. Vol. 7. No. 2. pp. 374-379.
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TY - JOUR
DO - 10.1039/c9qo01360a
UR - https://xlink.rsc.org/?DOI=C9QO01360A
TI - Cascade cyclization reactions of alkylidenecyclopropanes for the construction of polycyclic lactams and lactones by visible light photoredox catalysis
T2 - Organic Chemistry Frontiers
AU - Chen, Mintao
AU - Wei Yin, 尹维
AU - Shi, Min
PY - 2020
DA - 2020/01/01
PB - Royal Society of Chemistry (RSC)
SP - 374-379
IS - 2
VL - 7
SN - 2052-4110
SN - 2052-4129
ER -
Cite this
BibTex (up to 50 authors)
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@article{2020_Chen,
author = {Mintao Chen and 尹维 Wei Yin and Min Shi},
title = {Cascade cyclization reactions of alkylidenecyclopropanes for the construction of polycyclic lactams and lactones by visible light photoredox catalysis},
journal = {Organic Chemistry Frontiers},
year = {2020},
volume = {7},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://xlink.rsc.org/?DOI=C9QO01360A},
number = {2},
pages = {374--379},
doi = {10.1039/c9qo01360a}
}
Cite this
MLA
Copy
Chen, Mintao, et al. “Cascade cyclization reactions of alkylidenecyclopropanes for the construction of polycyclic lactams and lactones by visible light photoredox catalysis.” Organic Chemistry Frontiers, vol. 7, no. 2, Jan. 2020, pp. 374-379. https://xlink.rsc.org/?DOI=C9QO01360A.