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Chemodivergent synthesis of N-(pyridin-2-yl)amides and 3-bromoimidazo[1,2-a]pyridines from α-bromoketones and 2-aminopyridines
Тип публикации: Journal Article
Дата публикации: 2019-10-28
SCImago Q1
WOS Q2
БС1
SJR: 0.859
CiteScore: 8.7
Impact factor: 6.1
ISSN: 20462069
PubMed ID:
35529989
General Chemistry
General Chemical Engineering
Краткое описание
N-(Pyridin-2-yl)amides and 3-bromoimidazo[1,2-a]pyridines were synthesized respectively from α-bromoketones and 2-aminopyridine under different reaction conditions. N-(Pyridin-2-yl)amides were formed in toluene via C–C bond cleavage promoted by I2 and TBHP and the reaction conditions were mild and metal-free. Whereas 3-bromoimidazopyridines were obtained in ethyl acetate via one-pot tandem cyclization/bromination when only TBHP was added, the cyclization to form imidazopyridines was promoted by the further bromination, no base was needed, and the versatile 3-bromoimidazopyridines could be further transferred to other skeletons.
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ГОСТ
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Liu Y. et al. Chemodivergent synthesis of N-(pyridin-2-yl)amides and 3-bromoimidazo[1,2-a]pyridines from α-bromoketones and 2-aminopyridines // RSC Advances. 2019. Vol. 9. No. 59. pp. 34671-34676.
ГОСТ со всеми авторами (до 50)
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Liu Y., Lu L., Zhou H., Xu F., Ma C., Huang Z., Xu J., Xu S. Chemodivergent synthesis of N-(pyridin-2-yl)amides and 3-bromoimidazo[1,2-a]pyridines from α-bromoketones and 2-aminopyridines // RSC Advances. 2019. Vol. 9. No. 59. pp. 34671-34676.
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TY - JOUR
DO - 10.1039/C9RA06724H
UR - https://xlink.rsc.org/?DOI=C9RA06724H
TI - Chemodivergent synthesis of N-(pyridin-2-yl)amides and 3-bromoimidazo[1,2-a]pyridines from α-bromoketones and 2-aminopyridines
T2 - RSC Advances
AU - Liu, Yanpeng
AU - Lu, Lixue
AU - Zhou, Haipin
AU - Xu, Feijie
AU - Ma, Cong
AU - Huang, Zhangjian
AU - Xu, Jinyi
AU - Xu, Shengtao
PY - 2019
DA - 2019/10/28
PB - Royal Society of Chemistry (RSC)
SP - 34671-34676
IS - 59
VL - 9
PMID - 35529989
SN - 2046-2069
ER -
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@article{2019_Liu,
author = {Yanpeng Liu and Lixue Lu and Haipin Zhou and Feijie Xu and Cong Ma and Zhangjian Huang and Jinyi Xu and Shengtao Xu},
title = {Chemodivergent synthesis of N-(pyridin-2-yl)amides and 3-bromoimidazo[1,2-a]pyridines from α-bromoketones and 2-aminopyridines},
journal = {RSC Advances},
year = {2019},
volume = {9},
publisher = {Royal Society of Chemistry (RSC)},
month = {oct},
url = {https://xlink.rsc.org/?DOI=C9RA06724H},
number = {59},
pages = {34671--34676},
doi = {10.1039/C9RA06724H}
}
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MLA
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Liu, Yanpeng, et al. “Chemodivergent synthesis of N-(pyridin-2-yl)amides and 3-bromoimidazo[1,2-a]pyridines from α-bromoketones and 2-aminopyridines.” RSC Advances, vol. 9, no. 59, Oct. 2019, pp. 34671-34676. https://xlink.rsc.org/?DOI=C9RA06724H.
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