Open Access
Chemical Science, volume 10, issue 37, pages 8541-8546
Molybdenum and tungsten complexes with carbon dioxide and ethylene ligands
María Álvarez
1, 2, 3, 4, 5
,
Agustín Galindo
6, 7, 8, 9
,
Pedro J. Perez
1, 2, 3, 4, 5
,
Ernesto Carmona
6, 7, 10, 11, 12
2
Unidad Asociada al CSIC
3
CIQSO-Centro de Investigación en Química Sostenible
4
Departamento de Química
6
Departamento de Química Inorgánica
8
41071 Sevilla
9
SPAIN
|
10
Instituto de Investigaciones Químicas (IIQ)
11
Centro de Innovación en Química, Avanzada (ORFEO-CINQA)
12
Consejo Superior de Investigaciones Científicas (CSIC)
|
Publication type: Journal Article
Publication date: 2019-08-27
Journal:
Chemical Science
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 8.4
ISSN: 20416520, 20416539
General Chemistry
Abstract
The first examples of stable metal complexes with coordinated ethylene and carbon dioxide ligands are reported. Reaction of tris(ethylene) complexes mer-M(C2H4)3(PNP) (M = Mo and W; PNP = 2,6-bis(diphenylphosphinomethyl)pyridine) with CO2 yields the corresponding, mixed cis-M(C2H4)2(CO2)(PNP) derivatives. X-ray studies reveal six-coordinate structures exhibiting η2-ethylene and κ2-C,O carbon dioxide coordination. Remarkably, the formation of the molybdenum CO2 adduct occurs also in the solid state at room temperature, under 4 bar of CO2, in a nearly quantitative manner.
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GOST
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Álvarez M. et al. Molybdenum and tungsten complexes with carbon dioxide and ethylene ligands // Chemical Science. 2019. Vol. 10. No. 37. pp. 8541-8546.
GOST all authors (up to 50)
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Álvarez M., Galindo A., Perez P. J., Carmona E. Molybdenum and tungsten complexes with carbon dioxide and ethylene ligands // Chemical Science. 2019. Vol. 10. No. 37. pp. 8541-8546.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/c9sc03225h
UR - https://doi.org/10.1039/c9sc03225h
TI - Molybdenum and tungsten complexes with carbon dioxide and ethylene ligands
T2 - Chemical Science
AU - Galindo, Agustín
AU - Perez, Pedro J.
AU - Carmona, Ernesto
AU - Álvarez, María
PY - 2019
DA - 2019/08/27
PB - Royal Society of Chemistry (RSC)
SP - 8541-8546
IS - 37
VL - 10
SN - 2041-6520
SN - 2041-6539
ER -
Cite this
BibTex
Copy
@article{2019_Álvarez,
author = {Agustín Galindo and Pedro J. Perez and Ernesto Carmona and María Álvarez},
title = {Molybdenum and tungsten complexes with carbon dioxide and ethylene ligands},
journal = {Chemical Science},
year = {2019},
volume = {10},
publisher = {Royal Society of Chemistry (RSC)},
month = {aug},
url = {https://doi.org/10.1039/c9sc03225h},
number = {37},
pages = {8541--8546},
doi = {10.1039/c9sc03225h}
}
Cite this
MLA
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Álvarez, María, et al. “Molybdenum and tungsten complexes with carbon dioxide and ethylene ligands.” Chemical Science, vol. 10, no. 37, Aug. 2019, pp. 8541-8546. https://doi.org/10.1039/c9sc03225h.