Journal of Materials Chemistry A

, volume 7 , issue 20 , pages 12414-12419

Unprecedented plasmon-induced nitroxide-mediated polymerization (PI-NMP): a method for preparation of functional surfaces

Olga Guselnikova ^{1, 2, 3, 4, 5, 6, 7}

Sylvain R. A. Marque ^{8, 9, 10, 11, 12, 13}

Evgeny Tretyakov ^{14, 15, 16, 17, 18, 19, 20}

David Mares ^{6, 21, 22, 23, 24, 25}

Vitezslav Jerabek ^{6, 21, 22, 23, 24, 25}

Gérard Audran ^{8, 9, 10, 11, 12, 13}

Jean-Patrick Joly ^{8, 9, 10, 11, 12, 13}

Marina Trusova ^{2, 7, 26, 27}

Václav Švorčík ¹

Vaclav Svorcik ^{1, 3, 4, 5, 6}

Oleksiy Lyutakov ^{1, 2, 3, 4, 5, 6, 7}

Pavel S. Postnikov ^{1, 2, 3, 4, 5, 6, 7}

Hide authors affiliations Show authors affiliations: 27 affiliations

Department of Solid State Engineering, University of Chemistry and Technology, 16628 Prague, Czech Republic |

Research School of Chemistry and Applied Biomedical Sciences, Tomsk Polytechnic University, Russian Federation |

Department of Solid State Engineering

⁴

University of Chemistry and Technology |

⁵

16628 Prague |

⁶

Czech Republic |

⁷

Research School of Chemistry and Applied Biomedical Sciences

⁸

Aix Marseille Univ, CNRS, ICR, UMR 7273, case 551, Avenue Escadrille Normandie-Niemen, 13397 Marseille Cedex 20, France |

⁹

Aix Marseille univ |

¹⁰

CNRS

¹¹

ICR

¹²

UMR 7273

¹³

13397 Marseille Cedex 20 |

¹⁴

N. N. Vorozhtsov Institute of Organic Chemistry, Novosibirsk, Russia |

¹⁵

Novosibirsk State University, 2 Pirogova str., Novosibirsk 630090, Russia |

¹⁶

N. N. Vorozhtsov Institute of Organic Chemistry |

¹⁷

Novosibirsk |

¹⁸

Russia |

¹⁹

Novosibirsk State University |

²⁰

Novosibirsk 630090 |

²¹

Department of Microelectronics, Faculty of Electrical Engineering, Czech Technical University, Prague, Czech Republic |

²²

Department of Microelectronics

²³

Faculty of Electrical Engineering

²⁴

Czech Technical University |

²⁵

Prague |

²⁶

Tomsk polytechnic University |

²⁷

RUSSIAN FEDERATION |

Publication type: Journal Article

Publication date: 2019-04-01

Royal Society of Chemistry (RSC)

Journal of Materials Chemistry A

scimago Q1

wos Q1

SJR: 2.462

CiteScore: 16.7

Impact factor: 9.5

ISSN: 20507488, 20507496, 09599428, 13645501

DOI: 10.1039/C9TA01630A

Copy DOI

General Chemistry

General Materials Science

Renewable Energy, Sustainability and the Environment

Abstract

A plasmon as a stimulus opens up new opportunities for selective and regulated “from-surface” polymerization and functionalization of surfaces. Here, the first example of plasmon-assisted nitroxide-mediated polymerization (NMP) of stimuli-responsive block copolymers poly(N-isopropylacrylamide)-co-4-vinylboronic acid is reported. The growth of a polymer film at room temperature was achieved via plasmon-induced homolysis of alkoxyamines covalently attached to the surface of plasmon-active gold gratings at room temperature. Control of temperature, finite-difference time-domain method simulation of plasmon intensity distribution shift during polymerization, electron paramagnetic resonance experiments and other assays provide strong support for the plasmon-initiated mechanism of NMP. We demonstrated not only the control of the resulting polymer thickness but also the preparation of a surface-enhanced Raman spectroscopy chip for the detection of glycoproteins as a powerful example of plasmon-assisted NMP potential.

Found

15 citations

Postnikov Pavel

🥼

DSc in Chemistry

218 publications, 4 586 citations

h-index: 37

National Research Tomsk Polytechnic University

N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Metal-organic coordination polymers

Nanophotonics

Non-covalent Interactions

Organic Chemistry

Physical Chemistry

Plasmonics

Supramolecular chemistry

1 citation

Valiev Roman

🤝

PhD in Engineering

24 publications, 108 citations

h-index: 6

Ufa University of Science and Technology

Research interests

Intense plastic deformation

Mechanical properties of materials

Nanostructures

PVD coatings

The relationship of the chemical composition and structure of the material with its physical and mechanical properties

Titanium alloys

1 citation

Kinzhalov Mikhail

🥼 🤝

DSc in Chemistry, associate professor

94 publications, 1 894 citations

h-index: 27

National Research Tomsk Polytechnic University

Saint Petersburg State University

Research interests

Coordination Chemistry

Non-covalent Interactions

Organic Chemistry

Organometallic Chemistry

1 citation

Soldatova Natalia

🥼

PhD in Chemistry

34 publications, 653 citations, 5 reviews

h-index: 16

National Research Tomsk Polytechnic University

Research interests

Chemistry of hypervalent iodine compounds

Chemistry of nitrogen-containing heterocycles

Crystal Engineering

Organic synthesis

Supramolecular chemistry

1 citation

Kashina Maria

15 publications, 242 citations

h-index: 8

Saint Petersburg State University

Research interests

Chemistry of organic and organoelement compounds; chemistry of polymers; production of materials

Coordination Chemistry

Crystal Engineering

Photocatalysis

1 citation

Segida Oleg

15 publications, 251 citations

h-index: 8

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

1 citation

Krylov Igor

PhD in Chemistry

78 publications, 1 876 citations, 18 reviews

h-index: 25

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Research interests

Green chemistry

Organic Chemistry

Organic electrochemistry

Organic synthesis

Photochemistry

Plant protection

1 citation

Semin Viktor

PhD in Physics and Mathematics

70 publications, 459 citations, 15 reviews

h-index: 11

Institute of Strength Physics and Materials Science of the Siberian Branch of the Russian Academy of Sciences

Tomsk State University

Research interests

Alloys

Electrochemical corrosion

Electron microscopy

Solid State Physics

Thin films

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Guselnikova O. et al. Unprecedented plasmon-induced nitroxide-mediated polymerization (PI-NMP): a method for preparation of functional surfaces // Journal of Materials Chemistry A. 2019. Vol. 7. No. 20. pp. 12414-12419.

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RIS |

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RIS Copy

TY - JOUR

DO - 10.1039/C9TA01630A

UR - https://xlink.rsc.org/?DOI=C9TA01630A

TI - Unprecedented plasmon-induced nitroxide-mediated polymerization (PI-NMP): a method for preparation of functional surfaces

T2 - Journal of Materials Chemistry A

AU - Guselnikova, Olga

AU - Marque, Sylvain R. A.

AU - Tretyakov, Evgeny

AU - Mares, David

AU - Jerabek, Vitezslav

AU - Audran, Gérard

AU - Joly, Jean-Patrick

AU - Trusova, Marina

AU - Švorčík, Václav

AU - Svorcik, Vaclav

AU - Lyutakov, Oleksiy

AU - Postnikov, Pavel S.

PY - 2019

DA - 2019/04/01

PB - Royal Society of Chemistry (RSC)

SP - 12414-12419

IS - 20

VL - 7

SN - 2050-7488

SN - 2050-7496

SN - 0959-9428

SN - 1364-5501

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2019_Guselnikova,

author = {Olga Guselnikova and Sylvain R. A. Marque and Evgeny Tretyakov and David Mares and Vitezslav Jerabek and Gérard Audran and Jean-Patrick Joly and Marina Trusova and Václav Švorčík and Vaclav Svorcik and Oleksiy Lyutakov and Pavel S. Postnikov and others},

title = {Unprecedented plasmon-induced nitroxide-mediated polymerization (PI-NMP): a method for preparation of functional surfaces},

journal = {Journal of Materials Chemistry A},

year = {2019},

volume = {7},

publisher = {Royal Society of Chemistry (RSC)},

month = {apr},

url = {https://xlink.rsc.org/?DOI=C9TA01630A},

number = {20},

pages = {12414--12419},

doi = {10.1039/C9TA01630A}

}

MLA

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MLA Copy

Guselnikova, Olga, et al. “Unprecedented plasmon-induced nitroxide-mediated polymerization (PI-NMP): a method for preparation of functional surfaces.” Journal of Materials Chemistry A, vol. 7, no. 20, Apr. 2019, pp. 12414-12419. https://xlink.rsc.org/?DOI=C9TA01630A.

Publisher

Royal Society of Chemistry (RSC)

Journal

Journal of Materials Chemistry A

scimago Q1

wos Q1

SJR

2.462

CiteScore

16.7

Impact factor

9.5

ISSN

20507488 (Print)

20507496 (Electronic)

09599428 (Print)

13645501 (Electronic)

Labs

Laboratory of Organic Chemistry and Functional Materials

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