Chemical Communications

, том 56 , издание 48 , страницы 6527-6530

Aza-Henry and aza-Knoevenagel reactions of nitriles for the synthesis of pyrido[1,2-a]indoles

Тип публикации: Journal Article

Дата публикации: 2020-05-01

Royal Society of Chemistry (RSC)

Chemical Communications

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SJR: 0.907

CiteScore: 7.2

Impact factor: 4.3

ISSN: 13597345, 1364548X

DOI: 10.1039/d0cc01652g

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PubMed ID: 32395728

Materials Chemistry

Metals and Alloys

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General Chemistry

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N-(Propargyl)indole-2-carbonitriles undergo DBU-catalyzed addition of CH-acids to nitriles, followed by cyclization to give 9-aminopyrido[1,2-a]indoles. The reaction proceeds through the initial formation of a push–pull enamine, alkyne–allene rearrangement and intramolecular nucleophilic cyclization. Nitromethane and malonate esters can be employed as the CH-acids. The resulting compounds were found to exhibit fluorescence properties.

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Zalte R. R. et al. Aza-Henry and aza-Knoevenagel reactions of nitriles for the synthesis of pyrido[1,2-a]indoles // Chemical Communications. 2020. Vol. 56. No. 48. pp. 6527-6530.

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Zalte R. R., Festa A. A., Golantsov N. E., Karthikeyan S., Rybakov V. B., Varlamov A. V., Luque R., Voskressensky L. G. Aza-Henry and aza-Knoevenagel reactions of nitriles for the synthesis of pyrido[1,2-a]indoles // Chemical Communications. 2020. Vol. 56. No. 48. pp. 6527-6530.

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TY - JOUR

DO - 10.1039/d0cc01652g

UR - https://xlink.rsc.org/?DOI=D0CC01652G

TI - Aza-Henry and aza-Knoevenagel reactions of nitriles for the synthesis of pyrido[1,2-a]indoles

T2 - Chemical Communications

AU - Zalte, Rajesh R

AU - Festa, Alexey A.

AU - Golantsov, Nikita E

AU - Karthikeyan, Subramani

AU - Rybakov, Victor B.

AU - Varlamov, Alexey V.

AU - Luque, Rafael

AU - Voskressensky, Leonid G.

PY - 2020

DA - 2020/05/01

PB - Royal Society of Chemistry (RSC)

SP - 6527-6530

IS - 48

VL - 56

PMID - 32395728

SN - 1359-7345

SN - 1364-548X

ER -

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@article{2020_Zalte,

author = {Rajesh R Zalte and Alexey A. Festa and Nikita E Golantsov and Subramani Karthikeyan and Victor B. Rybakov and Alexey V. Varlamov and Rafael Luque and Leonid G. Voskressensky},

title = {Aza-Henry and aza-Knoevenagel reactions of nitriles for the synthesis of pyrido[1,2-a]indoles},

journal = {Chemical Communications},

year = {2020},

volume = {56},

publisher = {Royal Society of Chemistry (RSC)},

month = {may},

url = {https://xlink.rsc.org/?DOI=D0CC01652G},

number = {48},

pages = {6527--6530},

doi = {10.1039/d0cc01652g}

}

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Zalte, Rajesh R., et al. “Aza-Henry and aza-Knoevenagel reactions of nitriles for the synthesis of pyrido[1,2-a]indoles.” Chemical Communications, vol. 56, no. 48, May. 2020, pp. 6527-6530. https://xlink.rsc.org/?DOI=D0CC01652G.

Издатель

Royal Society of Chemistry (RSC)

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Chemical Communications

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БС1