volume 56 issue 44 pages 5953-5956

Understanding existing and designing novel synthetic routes to Pd-PEPPSI-NHC and Pd-PEPPSI-PR3pre-catalysts

Sébastien G Guillet 1, 2, 3, 4, 5
Vladislav A. Voloshkin 1, 2, 3, 4, 5
Marina Saab 1, 2, 3, 4, 5
Marek Beliš 1, 2, 3, 4, 5
Kristof Van Hecke 1, 2, 3, 4, 5
Fady Nahra 1, 2, 3, 4, 5, 6, 7
Steven P. Nolan 1, 2, 3, 4, 5
Publication typeJournal Article
Publication date2020-04-20
scimago Q1
wos Q2
SJR1.037
CiteScore7.4
Impact factor4.2
ISSN13597345, 1364548X
PubMed ID:  32347246
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Abstract
The reaction mechanism leading to the formation of cross-coupling palladium pre-catalysts of the PEPPSI family was investigated. Two intermediates were isolated and proved to be both suitable synthons to the pre-catalysts, with one permitting the design of a novel and greener user-friendly synthetic route. In light of this mechanistic understanding, the traditional one-pot method was shown to be possible using stoichiometric amounts of throw-away ligand, which represents a considerable synthetic improvement over the wasteful “in pyridine” approach.
Found 
Found 

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GOST Copy
Guillet S. G. et al. Understanding existing and designing novel synthetic routes to Pd-PEPPSI-NHC and Pd-PEPPSI-PR3pre-catalysts // Chemical Communications. 2020. Vol. 56. No. 44. pp. 5953-5956.
GOST all authors (up to 50) Copy
Guillet S. G., Voloshkin V. A., Saab M., Beliš M., Van Hecke K., Nahra F., Nolan S. P. Understanding existing and designing novel synthetic routes to Pd-PEPPSI-NHC and Pd-PEPPSI-PR3pre-catalysts // Chemical Communications. 2020. Vol. 56. No. 44. pp. 5953-5956.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1039/D0CC02262D
UR - https://xlink.rsc.org/?DOI=D0CC02262D
TI - Understanding existing and designing novel synthetic routes to Pd-PEPPSI-NHC and Pd-PEPPSI-PR3pre-catalysts
T2 - Chemical Communications
AU - Guillet, Sébastien G
AU - Voloshkin, Vladislav A.
AU - Saab, Marina
AU - Beliš, Marek
AU - Van Hecke, Kristof
AU - Nahra, Fady
AU - Nolan, Steven P.
PY - 2020
DA - 2020/04/20
PB - Royal Society of Chemistry (RSC)
SP - 5953-5956
IS - 44
VL - 56
PMID - 32347246
SN - 1359-7345
SN - 1364-548X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2020_Guillet,
author = {Sébastien G Guillet and Vladislav A. Voloshkin and Marina Saab and Marek Beliš and Kristof Van Hecke and Fady Nahra and Steven P. Nolan},
title = {Understanding existing and designing novel synthetic routes to Pd-PEPPSI-NHC and Pd-PEPPSI-PR3pre-catalysts},
journal = {Chemical Communications},
year = {2020},
volume = {56},
publisher = {Royal Society of Chemistry (RSC)},
month = {apr},
url = {https://xlink.rsc.org/?DOI=D0CC02262D},
number = {44},
pages = {5953--5956},
doi = {10.1039/D0CC02262D}
}
MLA
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MLA Copy
Guillet, Sébastien G., et al. “Understanding existing and designing novel synthetic routes to Pd-PEPPSI-NHC and Pd-PEPPSI-PR3pre-catalysts.” Chemical Communications, vol. 56, no. 44, Apr. 2020, pp. 5953-5956. https://xlink.rsc.org/?DOI=D0CC02262D.