volume 56 issue 66 pages 9453-9456

Fluoroalkyl sulfides as photoredox-active coupling reagents for alkene difunctionalization

Mikhail D Kosobokov 1, 2, 3, 4
Mikhail O Zubkov 1, 2, 3, 4
Vitalij V Levin 1, 2, 3, 4
Alexander D Dilman 1, 2, 3, 4
Publication typeJournal Article
Publication date2020-07-08
scimago Q1
wos Q2
SJR1.037
CiteScore7.4
Impact factor4.2
ISSN13597345, 1364548X
PubMed ID:  32677653
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Abstract
A visible-light-promoted fluoroalkylation-thiolation of alkenes is described. A 4-tetrafluoropyridinylthio fragment serves as a photoredox-active group in the initiation step and undergoes a radical group transfer, which is important for the reaction efficiency. In the primary products, the pyridinylthio substituent may be further functionalized via radical processes or an aromatic substitution reaction.
Found 
Found 

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GOST Copy
Kosobokov M. D. et al. Fluoroalkyl sulfides as photoredox-active coupling reagents for alkene difunctionalization // Chemical Communications. 2020. Vol. 56. No. 66. pp. 9453-9456.
GOST all authors (up to 50) Copy
Kosobokov M. D., Zubkov M. O., Levin V. V., Kokorekin V. A., Dilman A. D. Fluoroalkyl sulfides as photoredox-active coupling reagents for alkene difunctionalization // Chemical Communications. 2020. Vol. 56. No. 66. pp. 9453-9456.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1039/D0CC04617E
UR - https://xlink.rsc.org/?DOI=D0CC04617E
TI - Fluoroalkyl sulfides as photoredox-active coupling reagents for alkene difunctionalization
T2 - Chemical Communications
AU - Kosobokov, Mikhail D
AU - Zubkov, Mikhail O
AU - Levin, Vitalij V
AU - Kokorekin, Vladimir A.
AU - Dilman, Alexander D
PY - 2020
DA - 2020/07/08
PB - Royal Society of Chemistry (RSC)
SP - 9453-9456
IS - 66
VL - 56
PMID - 32677653
SN - 1359-7345
SN - 1364-548X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2020_Kosobokov,
author = {Mikhail D Kosobokov and Mikhail O Zubkov and Vitalij V Levin and Vladimir A. Kokorekin and Alexander D Dilman},
title = {Fluoroalkyl sulfides as photoredox-active coupling reagents for alkene difunctionalization},
journal = {Chemical Communications},
year = {2020},
volume = {56},
publisher = {Royal Society of Chemistry (RSC)},
month = {jul},
url = {https://xlink.rsc.org/?DOI=D0CC04617E},
number = {66},
pages = {9453--9456},
doi = {10.1039/D0CC04617E}
}
MLA
Cite this
MLA Copy
Kosobokov, Mikhail D., et al. “Fluoroalkyl sulfides as photoredox-active coupling reagents for alkene difunctionalization.” Chemical Communications, vol. 56, no. 66, Jul. 2020, pp. 9453-9456. https://xlink.rsc.org/?DOI=D0CC04617E.