CrystEngComm, volume 23, issue 12, pages 2384-2395

Synthesis and supramolecular organization of the iodide and triiodides of a polycyclic adamantane-based diammonium cation: the effects of hydrogen bonds and weak I⋯I interactions

Publication typeJournal Article
Publication date2021-02-24
Journal: CrystEngComm
Quartile SCImago
Q2
Quartile WOS
Q1
Impact factor3.1
ISSN14668033
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
A careful selection of organic and inorganic components enables the production of unusual structure types with promising practical properties by facile syntheses. In this paper, we describe novel supramolecular architectures comprising organic adamantane-like divalent building blocks and iodide or polyiodide anions. Highly acidic conditions facilitated the formation of a doubly protonated organic ligand out of 5,7-dimethyl-1,3-diazaadamantane that generates three different crystal structures with inorganic counterions. In these structures, cationic substructures are constructed by transforming neutral organic ligands into [(C10N2H20)I]+ or [(C10N2H20)(H2O)]2+ cations, which crystallize with charge-compensating iodine-based anions of different complexities. All three crystal structures are characterized by various noncovalent forces, ranging from strong (N)H⋯I, (O)H⋯I, and (N)H⋯O hydrogen bonds to secondary and weak I⋯I interactions. Raman and diffuse reflectance spectroscopy as well as DFT calculations were employed to describe the electronic structures and optical properties of new supramolecular architectures, with particular attention to the role of non-covalent interactions.

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Mezentsev Cherkes I. A. et al. Synthesis and supramolecular organization of the iodide and triiodides of a polycyclic adamantane-based diammonium cation: the effects of hydrogen bonds and weak I⋯I interactions // CrystEngComm. 2021. Vol. 23. No. 12. pp. 2384-2395.
GOST all authors (up to 50) Copy
Mezentsev Cherkes I. A., Shestimerova T. A., Medved'ko A. V., Kalinin M. A., Kuznetsov A. N., Wei Z., Dikarev E. V., Vatsadze S. Z., Shevelkov A. V. Synthesis and supramolecular organization of the iodide and triiodides of a polycyclic adamantane-based diammonium cation: the effects of hydrogen bonds and weak I⋯I interactions // CrystEngComm. 2021. Vol. 23. No. 12. pp. 2384-2395.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1039/D0CE01730B
UR - https://doi.org/10.1039%2FD0CE01730B
TI - Synthesis and supramolecular organization of the iodide and triiodides of a polycyclic adamantane-based diammonium cation: the effects of hydrogen bonds and weak I⋯I interactions
T2 - CrystEngComm
AU - Mezentsev Cherkes, Ivan A
AU - Kuznetsov, Alexey N.
AU - Dikarev, Evgeny V.
AU - Vatsadze, Sergey Z.
AU - Shevelkov, Andrei V.
AU - Medved'ko, Aleksei V.
AU - Kalinin, Mikhail A
AU - Shestimerova, Tatiana A
AU - Wei, Zheng
PY - 2021
DA - 2021/02/24 00:00:00
PB - Royal Society of Chemistry (RSC)
SP - 2384-2395
IS - 12
VL - 23
SN - 1466-8033
ER -
BibTex |
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BibTex Copy
@article{2021_Mezentsev Cherkes
author = {Ivan A Mezentsev Cherkes and Alexey N. Kuznetsov and Evgeny V. Dikarev and Sergey Z. Vatsadze and Andrei V. Shevelkov and Aleksei V. Medved'ko and Mikhail A Kalinin and Tatiana A Shestimerova and Zheng Wei},
title = {Synthesis and supramolecular organization of the iodide and triiodides of a polycyclic adamantane-based diammonium cation: the effects of hydrogen bonds and weak I⋯I interactions},
journal = {CrystEngComm},
year = {2021},
volume = {23},
publisher = {Royal Society of Chemistry (RSC)},
month = {feb},
url = {https://doi.org/10.1039%2FD0CE01730B},
number = {12},
pages = {2384--2395},
doi = {10.1039/D0CE01730B}
}
MLA
Cite this
MLA Copy
Mezentsev Cherkes, Ivan A., et al. “Synthesis and supramolecular organization of the iodide and triiodides of a polycyclic adamantane-based diammonium cation: the effects of hydrogen bonds and weak I⋯I interactions.” CrystEngComm, vol. 23, no. 12, Feb. 2021, pp. 2384-2395. https://doi.org/10.1039%2FD0CE01730B.
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