Dalton Transactions, volume 49, issue 35, pages 12156-12160

How does the ligand affect the sensitivity of the luminescent thermometers based on Tb-Eu complexes.

Publication typeJournal Article
Publication date2020-08-06
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor4
ISSN14779226, 14779234
Inorganic Chemistry
Abstract
Theoretical description of a four-level system for luminescent thermometry was proposed. Based on this description, the sensitivity was proved not to exceed Sr =|E23 - E12|/T2, where T is the temperature and |E23 - E12| is the absolute energy difference between the excited state energy gaps. The analysis was verified for the terbium-europium coordination compounds, the most studied class of four-level thermometry systems, which revealed that most of the examples fall within either this theory or represent three-level systems, where the ligand is not involved in the thermally-activated processes. From this description, it follows that the highest Sr can be reached either when the triplet state is not involved or when the ligand triplet state is very high, which in the case of terbium-europium coordination compounds means exceeding 26 800 cm-1.

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Popelensky T., Utochnikova V. How does the ligand affect the sensitivity of the luminescent thermometers based on Tb-Eu complexes. // Dalton Transactions. 2020. Vol. 49. No. 35. pp. 12156-12160.
GOST all authors (up to 50) Copy
Popelensky T., Utochnikova V. How does the ligand affect the sensitivity of the luminescent thermometers based on Tb-Eu complexes. // Dalton Transactions. 2020. Vol. 49. No. 35. pp. 12156-12160.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1039/D0DT02238A
UR - https://doi.org/10.1039%2FD0DT02238A
TI - How does the ligand affect the sensitivity of the luminescent thermometers based on Tb-Eu complexes.
T2 - Dalton Transactions
AU - Popelensky, Th.Yu.
AU - Utochnikova, Valentina
PY - 2020
DA - 2020/08/06 00:00:00
PB - Royal Society of Chemistry (RSC)
SP - 12156-12160
IS - 35
VL - 49
SN - 1477-9226
SN - 1477-9234
ER -
BibTex |
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BibTex Copy
@article{2020_Popelensky
author = {Th.Yu. Popelensky and Valentina Utochnikova},
title = {How does the ligand affect the sensitivity of the luminescent thermometers based on Tb-Eu complexes.},
journal = {Dalton Transactions},
year = {2020},
volume = {49},
publisher = {Royal Society of Chemistry (RSC)},
month = {aug},
url = {https://doi.org/10.1039%2FD0DT02238A},
number = {35},
pages = {12156--12160},
doi = {10.1039/D0DT02238A}
}
MLA
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MLA Copy
Popelensky, Th.Yu., and Valentina Utochnikova. “How does the ligand affect the sensitivity of the luminescent thermometers based on Tb-Eu complexes..” Dalton Transactions, vol. 49, no. 35, Aug. 2020, pp. 12156-12160. https://doi.org/10.1039%2FD0DT02238A.
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