Cyclometalated Ru(II) complexes with tunable redox and optical properties for dye-sensitized solar cells
Maria A Lavrova
1, 2, 3, 4
,
Sergey A Mishurinskiy
1, 2, 3, 4
,
Daniil E. Smirnov
1, 2, 3, 4, 5, 6, 7
,
Paulina Kalle
1, 2, 3, 4, 5, 6, 7
,
Ekaterina V Krivogina
4, 5, 6, 7, 8
,
V. V. Emets
9
,
Viktor V Emets
4, 7, 10, 11
,
Sofia S Mariasina
1, 2, 3, 4
,
Vladimir D. Dolzhenko
1, 2, 3, 4, 7, 12, 13
,
Stanislav I. Bezzubov
4, 5, 6, 7, 8
3
Moscow
4
Russia
|
7
RUSSIAN ACADEMY OF SCIENCES
8
Moscow 119991
11
Moscow 119071
Publication type: Journal Article
Publication date: 2020-10-28
scimago Q2
wos Q1
SJR: 0.653
CiteScore: 6.0
Impact factor: 3.3
ISSN: 14779226, 14779234
PubMed ID:
33188375
Inorganic Chemistry
Abstract
Cyclometalated Ru(II) complexes with 2-arylbenzimidazole antenna ligands bearing electron-donor/withdrawing substituents and anchoring 4,4′-dimethoxycarbonyl-2,2′-bipyridine have been prepared and their structure, optical and electrochemical properties have been studied. The complexes possess enhanced light-harvesting characteristics compared to those of the standard N719 dye and absorb light up to 750 nm. In addition, they demonstrate reversible redox behavior with Ru3+/Ru2+ potentials being finely tuned by the change of the electron-donating ability of cyclometalated ligands. After a mild hydrolysis of dimethoxycarbonyl groups the excellent optical properties of the complexes remain unchanged and they show good efficiency when tested in dye-sensitized solar cells.
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Total citations:
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Citations from 2024:
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(29%)
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Lavrova M. A. et al. Cyclometalated Ru(II) complexes with tunable redox and optical properties for dye-sensitized solar cells // Dalton Transactions. 2020. Vol. 49. No. 46. pp. 16935-16945.
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Lavrova M. A., Mishurinskiy S. A., Smirnov D. E., Kalle P., Krivogina E. V., Kozyukhin S. A., Emets V. V., Emets V. V., Mariasina S. S., Dolzhenko V. D., Bezzubov S. I. Cyclometalated Ru(II) complexes with tunable redox and optical properties for dye-sensitized solar cells // Dalton Transactions. 2020. Vol. 49. No. 46. pp. 16935-16945.
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TY - JOUR
DO - 10.1039/D0DT03564E
UR - https://xlink.rsc.org/?DOI=D0DT03564E
TI - Cyclometalated Ru(II) complexes with tunable redox and optical properties for dye-sensitized solar cells
T2 - Dalton Transactions
AU - Lavrova, Maria A
AU - Mishurinskiy, Sergey A
AU - Smirnov, Daniil E.
AU - Kalle, Paulina
AU - Krivogina, Ekaterina V
AU - Kozyukhin, Sergey A.
AU - Emets, V. V.
AU - Emets, Viktor V
AU - Mariasina, Sofia S
AU - Dolzhenko, Vladimir D.
AU - Bezzubov, Stanislav I.
PY - 2020
DA - 2020/10/28
PB - Royal Society of Chemistry (RSC)
SP - 16935-16945
IS - 46
VL - 49
PMID - 33188375
SN - 1477-9226
SN - 1477-9234
ER -
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BibTex (up to 50 authors)
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@article{2020_Lavrova,
author = {Maria A Lavrova and Sergey A Mishurinskiy and Daniil E. Smirnov and Paulina Kalle and Ekaterina V Krivogina and Sergey A. Kozyukhin and V. V. Emets and Viktor V Emets and Sofia S Mariasina and Vladimir D. Dolzhenko and Stanislav I. Bezzubov},
title = {Cyclometalated Ru(II) complexes with tunable redox and optical properties for dye-sensitized solar cells},
journal = {Dalton Transactions},
year = {2020},
volume = {49},
publisher = {Royal Society of Chemistry (RSC)},
month = {oct},
url = {https://xlink.rsc.org/?DOI=D0DT03564E},
number = {46},
pages = {16935--16945},
doi = {10.1039/D0DT03564E}
}
Cite this
MLA
Copy
Lavrova, Maria A., et al. “Cyclometalated Ru(II) complexes with tunable redox and optical properties for dye-sensitized solar cells.” Dalton Transactions, vol. 49, no. 46, Oct. 2020, pp. 16935-16945. https://xlink.rsc.org/?DOI=D0DT03564E.