Highly NIR-emitting ytterbium complexes containing 2-(tosylaminobenzylidene)-N-benzoylhydrazone anions: structure in solution and use for bioimaging.
Anton Kovalenko
1, 2, 3, 4, 5, 6, 7
,
Alexander A Pavlov
5, 6, 8, 9
,
Ilya D Ustinovich
5, 6, 8, 9
,
Alena S Kalyakina
10, 11, 12, 13, 14, 15
,
Lukasz Marciniak
16, 17, 18, 19, 20
,
Leonid S. Lepnev
5, 6, 21, 22
,
A.S Burlov
23
,
Anatolii S. Burlov
6, 24, 25, 26
,
U. Schepers
27, 28
,
Ute Schepers
12, 13, 15, 29, 30
,
Stefan Bräse
10, 28
,
Valentina Utochnikova
1, 3, 4, 5, 6, 31, 32
2
Center for Molecular Biophysics, CNRS (UPR 4301), Orléans, France
|
3
Department of Material Sciences
5
Moscow
6
RUSSIAN FEDERATION
|
7
Center for Molecular Biophysics
11
Institute of Biological and Chemical Systems (IBCS-FMS)
13
Hermann von Helmholtz Platz 1
14
KarlsruheEggenstein-Leopolddshafen
|
15
GERMANY
|
16
18
Polish Academy Of Sciences
|
19
Wroclaw
|
20
POLAND
|
26
Rostov-on-Don
|
29
Institute of Functional Interfaces (IFG)
30
Eggenstein-Leopolddshafen
Publication type: Journal Article
Publication date: 2021-02-11
scimago Q2
wos Q1
SJR: 0.653
CiteScore: 6.0
Impact factor: 3.3
ISSN: 14779226, 14779234
PubMed ID:
33704306
Inorganic Chemistry
Abstract
Solution behaviour in DMSO using 1D and 2D NMR spectroscopy was performed for lanthanide complexes Ln(L)(HL) and Ln(HL)2Cl, containing non-macrocyclic 2-(tosylamino)-benzylidene-N-benzoylhydrazone (H2L), and the structure of [Yb(L)]+ cation in solution was determined. Based on the NMR data, the possibility to obtain novel complexes containing [Ln(L)2]- was predicted, which was successfully synthesized, and the crystal structure of K(C2H5OH)3[Yb(L)2] was determined. Thanks to its high quantum yield of NIR luminescence (1.3 ± 0.2%), high absorption, low toxicity, and the stability of its anion against dissociation in DMSO, K(H2O)3[Yb(L)2] was successfully used for bioimaging.
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Total citations:
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Citations from 2024:
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GOST
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Kovalenko A. et al. Highly NIR-emitting ytterbium complexes containing 2-(tosylaminobenzylidene)-N-benzoylhydrazone anions: structure in solution and use for bioimaging. // Dalton Transactions. 2021. Vol. 50. No. 11. pp. 3786-3791.
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Kovalenko A. et al. Highly NIR-emitting ytterbium complexes containing 2-(tosylaminobenzylidene)-N-benzoylhydrazone anions: structure in solution and use for bioimaging. // Dalton Transactions. 2021. Vol. 50. No. 11. pp. 3786-3791.
Cite this
RIS
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TY - JOUR
DO - 10.1039/D0DT03913F
UR - https://xlink.rsc.org/?DOI=D0DT03913F
TI - Highly NIR-emitting ytterbium complexes containing 2-(tosylaminobenzylidene)-N-benzoylhydrazone anions: structure in solution and use for bioimaging.
T2 - Dalton Transactions
AU - Kovalenko, Anton
AU - Pavlov, Alexander A
AU - Ustinovich, Ilya D
AU - Kalyakina, Alena S
AU - Goloveshkin, Alexander S.
AU - Marciniak, Lukasz
AU - Lepnev, Leonid S.
AU - Burlov, A.S
AU - Burlov, Anatolii S.
AU - Schepers, U.
AU - Schepers, Ute
AU - Bräse, Stefan
AU - Utochnikova, Valentina
PY - 2021
DA - 2021/02/11
PB - Royal Society of Chemistry (RSC)
SP - 3786-3791
IS - 11
VL - 50
PMID - 33704306
SN - 1477-9226
SN - 1477-9234
ER -
Cite this
BibTex (up to 50 authors)
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@article{2021_Kovalenko,
author = {Anton Kovalenko and Alexander A Pavlov and Ilya D Ustinovich and Alena S Kalyakina and Alexander S. Goloveshkin and Lukasz Marciniak and Leonid S. Lepnev and A.S Burlov and Anatolii S. Burlov and U. Schepers and Ute Schepers and Stefan Bräse and Valentina Utochnikova and others},
title = {Highly NIR-emitting ytterbium complexes containing 2-(tosylaminobenzylidene)-N-benzoylhydrazone anions: structure in solution and use for bioimaging.},
journal = {Dalton Transactions},
year = {2021},
volume = {50},
publisher = {Royal Society of Chemistry (RSC)},
month = {feb},
url = {https://xlink.rsc.org/?DOI=D0DT03913F},
number = {11},
pages = {3786--3791},
doi = {10.1039/D0DT03913F}
}
Cite this
MLA
Copy
Kovalenko, Anton, et al. “Highly NIR-emitting ytterbium complexes containing 2-(tosylaminobenzylidene)-N-benzoylhydrazone anions: structure in solution and use for bioimaging..” Dalton Transactions, vol. 50, no. 11, Feb. 2021, pp. 3786-3791. https://xlink.rsc.org/?DOI=D0DT03913F.