Dalton Transactions, volume 50, issue 11, pages 3786-3791
Highly NIR-emitting ytterbium complexes containing 2-(tosylaminobenzylidene)-N-benzoylhydrazone anions: structure in solution and use for bioimaging.
Kovalenko Anton
1, 2
,
Ustinovich Ilya D
3
,
Marciniak Lukasz
5
,
Lepnev Leonid S.
6
,
Burlov A.S
7
,
Schepers U.
8, 9
,
Bräse Stefan
4, 9
,
Utochnikova Valentina
1, 10
2
Center for Molecular Biophysics, CNRS (UPR 4301), Orléans, France
|
5
Institute of Low temperature and Structure Research, Polish Academy of Sciences, Wroclaw, Poland
|
Publication type: Journal Article
Publication date: 2021-02-11
Journal:
Dalton Transactions
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 4
ISSN: 14779226, 14779234
Inorganic Chemistry
Abstract
Solution behaviour in DMSO using 1D and 2D NMR spectroscopy was performed for lanthanide complexes Ln(L)(HL) and Ln(HL)2Cl, containing non-macrocyclic 2-(tosylamino)-benzylidene-N-benzoylhydrazone (H2L), and the structure of [Yb(L)]+ cation in solution was determined. Based on the NMR data, the possibility to obtain novel complexes containing [Ln(L)2]- was predicted, which was successfully synthesized, and the crystal structure of K(C2H5OH)3[Yb(L)2] was determined. Thanks to its high quantum yield of NIR luminescence (1.3 ± 0.2%), high absorption, low toxicity, and the stability of its anion against dissociation in DMSO, K(H2O)3[Yb(L)2] was successfully used for bioimaging.
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1 publication, 9.09%
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1 publication, 9.09%
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Citations by publishers
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1
2
3
4
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Elsevier
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4 publications, 36.36%
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2 publications, 18.18%
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Wiley
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2 publications, 18.18%
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Pleiades Publishing
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Pleiades Publishing
1 publication, 9.09%
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1
2
3
4
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Kovalenko A. et al. Highly NIR-emitting ytterbium complexes containing 2-(tosylaminobenzylidene)-N-benzoylhydrazone anions: structure in solution and use for bioimaging. // Dalton Transactions. 2021. Vol. 50. No. 11. pp. 3786-3791.
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Kovalenko A., Pavlov A. A., Ustinovich I. D., Kalyakina A. S., Goloveshkin A. S., Marciniak L., Lepnev L. S., Burlov A., Schepers U., Bräse S., Utochnikova V. Highly NIR-emitting ytterbium complexes containing 2-(tosylaminobenzylidene)-N-benzoylhydrazone anions: structure in solution and use for bioimaging. // Dalton Transactions. 2021. Vol. 50. No. 11. pp. 3786-3791.
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TY - JOUR
DO - 10.1039/D0DT03913F
UR - https://doi.org/10.1039%2FD0DT03913F
TI - Highly NIR-emitting ytterbium complexes containing 2-(tosylaminobenzylidene)-N-benzoylhydrazone anions: structure in solution and use for bioimaging.
T2 - Dalton Transactions
AU - Kovalenko, Anton
AU - Pavlov, Alexander A
AU - Ustinovich, Ilya D
AU - Kalyakina, Alena S
AU - Marciniak, Lukasz
AU - Lepnev, Leonid S.
AU - Utochnikova, Valentina
AU - Goloveshkin, Alexander S.
AU - Burlov, A.S
AU - Schepers, U.
AU - Bräse, Stefan
PY - 2021
DA - 2021/02/11 00:00:00
PB - Royal Society of Chemistry (RSC)
SP - 3786-3791
IS - 11
VL - 50
SN - 1477-9226
SN - 1477-9234
ER -
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@article{2021_Kovalenko,
author = {Anton Kovalenko and Alexander A Pavlov and Ilya D Ustinovich and Alena S Kalyakina and Lukasz Marciniak and Leonid S. Lepnev and Valentina Utochnikova and Alexander S. Goloveshkin and A.S Burlov and U. Schepers and Stefan Bräse},
title = {Highly NIR-emitting ytterbium complexes containing 2-(tosylaminobenzylidene)-N-benzoylhydrazone anions: structure in solution and use for bioimaging.},
journal = {Dalton Transactions},
year = {2021},
volume = {50},
publisher = {Royal Society of Chemistry (RSC)},
month = {feb},
url = {https://doi.org/10.1039%2FD0DT03913F},
number = {11},
pages = {3786--3791},
doi = {10.1039/D0DT03913F}
}
Cite this
MLA
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Kovalenko, Anton, et al. “Highly NIR-emitting ytterbium complexes containing 2-(tosylaminobenzylidene)-N-benzoylhydrazone anions: structure in solution and use for bioimaging..” Dalton Transactions, vol. 50, no. 11, Feb. 2021, pp. 3786-3791. https://doi.org/10.1039%2FD0DT03913F.