Highly NIR-emitting ytterbium complexes containing 2-(tosylaminobenzylidene)-N-benzoylhydrazone anions: structure in solution and use for bioimaging.
Тип публикации: Journal Article
Дата публикации: 2021-02-11
scimago Q2
wos Q1
БС1
SJR: 0.653
CiteScore: 6.0
Impact factor: 3.3
ISSN: 14779226, 14779234
PubMed ID:
33704306
Inorganic Chemistry
Краткое описание
Solution behaviour in DMSO using 1D and 2D NMR spectroscopy was performed for lanthanide complexes Ln(L)(HL) and Ln(HL)2Cl, containing non-macrocyclic 2-(tosylamino)-benzylidene-N-benzoylhydrazone (H2L), and the structure of [Yb(L)]+ cation in solution was determined. Based on the NMR data, the possibility to obtain novel complexes containing [Ln(L)2]- was predicted, which was successfully synthesized, and the crystal structure of K(C2H5OH)3[Yb(L)2] was determined. Thanks to its high quantum yield of NIR luminescence (1.3 ± 0.2%), high absorption, low toxicity, and the stability of its anion against dissociation in DMSO, K(H2O)3[Yb(L)2] was successfully used for bioimaging.
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Kovalenko A. et al. Highly NIR-emitting ytterbium complexes containing 2-(tosylaminobenzylidene)-N-benzoylhydrazone anions: structure in solution and use for bioimaging. // Dalton Transactions. 2021. Vol. 50. No. 11. pp. 3786-3791.
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Kovalenko A. et al. Highly NIR-emitting ytterbium complexes containing 2-(tosylaminobenzylidene)-N-benzoylhydrazone anions: structure in solution and use for bioimaging. // Dalton Transactions. 2021. Vol. 50. No. 11. pp. 3786-3791.
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TY - JOUR
DO - 10.1039/D0DT03913F
UR - https://xlink.rsc.org/?DOI=D0DT03913F
TI - Highly NIR-emitting ytterbium complexes containing 2-(tosylaminobenzylidene)-N-benzoylhydrazone anions: structure in solution and use for bioimaging.
T2 - Dalton Transactions
AU - Kovalenko, Anton
AU - Pavlov, Alexander A
AU - Ustinovich, Ilya D
AU - Kalyakina, Alena S
AU - Goloveshkin, Alexander S.
AU - Marciniak, Lukasz
AU - Lepnev, Leonid S.
AU - Burlov, A.S
AU - Burlov, Anatolii S.
AU - Schepers, U.
AU - Schepers, Ute
AU - Bräse, Stefan
AU - Utochnikova, Valentina
PY - 2021
DA - 2021/02/11
PB - Royal Society of Chemistry (RSC)
SP - 3786-3791
IS - 11
VL - 50
PMID - 33704306
SN - 1477-9226
SN - 1477-9234
ER -
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@article{2021_Kovalenko,
author = {Anton Kovalenko and Alexander A Pavlov and Ilya D Ustinovich and Alena S Kalyakina and Alexander S. Goloveshkin and Lukasz Marciniak and Leonid S. Lepnev and A.S Burlov and Anatolii S. Burlov and U. Schepers and Ute Schepers and Stefan Bräse and Valentina Utochnikova and others},
title = {Highly NIR-emitting ytterbium complexes containing 2-(tosylaminobenzylidene)-N-benzoylhydrazone anions: structure in solution and use for bioimaging.},
journal = {Dalton Transactions},
year = {2021},
volume = {50},
publisher = {Royal Society of Chemistry (RSC)},
month = {feb},
url = {https://xlink.rsc.org/?DOI=D0DT03913F},
number = {11},
pages = {3786--3791},
doi = {10.1039/D0DT03913F}
}
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Kovalenko, Anton, et al. “Highly NIR-emitting ytterbium complexes containing 2-(tosylaminobenzylidene)-N-benzoylhydrazone anions: structure in solution and use for bioimaging..” Dalton Transactions, vol. 50, no. 11, Feb. 2021, pp. 3786-3791. https://xlink.rsc.org/?DOI=D0DT03913F.