Chemical Communications, volume 57, issue 85, pages 11201-11204
Construction of an isoquinolinone framework from carboxylic-ester-directed umpolung ring opening of methylenecyclopropanes
Publication type: Journal Article
Publication date: 2021-09-27
Journal:
Chemical Communications
Q1
Q2
SJR: 1.133
CiteScore: 8.6
Impact factor: 4.3
ISSN: 13597345, 1364548X
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Abstract
An interesting type of reaction involving functionalized methylenecyclopropanes (MCPs) has been revealed. Here, a nucleophilic attack of an anionic species onto a partially polarity-reversed MCP was realized by treating a neighbouring carboxylic ester tethered to the MCP and amine with KHMDS to realize an umpolung ring opening of the MCP. This work established an operationally convenient protocol for the rapid construction of isoquinolinone frameworks.
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Wei H. Z. et al. Construction of an isoquinolinone framework from carboxylic-ester-directed umpolung ring opening of methylenecyclopropanes // Chemical Communications. 2021. Vol. 57. No. 85. pp. 11201-11204.
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Wei H. Z., Wei H., Wei Yin 尹., Shi M. Construction of an isoquinolinone framework from carboxylic-ester-directed umpolung ring opening of methylenecyclopropanes // Chemical Communications. 2021. Vol. 57. No. 85. pp. 11201-11204.
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TY - JOUR
DO - 10.1039/d1cc04826k
UR - https://doi.org/10.1039/d1cc04826k
TI - Construction of an isoquinolinone framework from carboxylic-ester-directed umpolung ring opening of methylenecyclopropanes
T2 - Chemical Communications
AU - Wei, Hao Zhao
AU - Wei, Hao-Zhao
AU - Wei Yin, 尹维
AU - Shi, Min
PY - 2021
DA - 2021/09/27
PB - Royal Society of Chemistry (RSC)
SP - 11201-11204
IS - 85
VL - 57
SN - 1359-7345
SN - 1364-548X
ER -
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BibTex (up to 50 authors)
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@article{2021_Wei,
author = {Hao Zhao Wei and Hao-Zhao Wei and 尹维 Wei Yin and Min Shi},
title = {Construction of an isoquinolinone framework from carboxylic-ester-directed umpolung ring opening of methylenecyclopropanes},
journal = {Chemical Communications},
year = {2021},
volume = {57},
publisher = {Royal Society of Chemistry (RSC)},
month = {sep},
url = {https://doi.org/10.1039/d1cc04826k},
number = {85},
pages = {11201--11204},
doi = {10.1039/d1cc04826k}
}
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Wei, Hao Zhao, et al. “Construction of an isoquinolinone framework from carboxylic-ester-directed umpolung ring opening of methylenecyclopropanes.” Chemical Communications, vol. 57, no. 85, Sep. 2021, pp. 11201-11204. https://doi.org/10.1039/d1cc04826k.