Deprotonated diaminocarbene platinum complexes for thermoresponsive luminescent silicone materials: both catalysts and luminophores.
Andrey V Dobrynin
1, 2
,
Svetlana O Kasatkina
1, 2
,
Sergey V Baykov
1, 2
,
Polina Y Savko
1, 2
,
N S Antonov
1, 2
,
Alexander Mikherdov
1, 2
,
Vadim P Boyarskiy
1, 2
,
Regina M Islamova
1, 2
Тип публикации: Journal Article
Дата публикации: 2021-10-11
scimago Q2
wos Q1
БС1
SJR: 0.653
CiteScore: 6.0
Impact factor: 3.3
ISSN: 14779226, 14779234
PubMed ID:
34693947
Inorganic Chemistry
Краткое описание
C,N-Chelate deprotonated diaminocarbene platinum(II) complexes were synthesized by coupling coordinated isocyanides and azinyl-substituted ureas. The complexes act as catalysts of α,ω-divinylpolydimethylsiloxane and poly(dimethylsiloxane-co-methylhydrosiloxane) hydrosilylation cross-linking. Silicone rubbers obtained with (aminoisoquinoline)-containing complex 3d exhibit temperature-responsive luminescence. Their emission changes irreversibly when heated from 80-100 °C (green radiation) to 120 °C or more (blue radiation).
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Dobrynin A. V. et al. Deprotonated diaminocarbene platinum complexes for thermoresponsive luminescent silicone materials: both catalysts and luminophores. // Dalton Transactions. 2021. Vol. 50. No. 42. pp. 14994-14999.
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Dobrynin A. V., Kasatkina S. O., Baykov S. V., Savko P. Y., Antonov N. S., Mikherdov A., Boyarskiy V. P., Islamova R. M. Deprotonated diaminocarbene platinum complexes for thermoresponsive luminescent silicone materials: both catalysts and luminophores. // Dalton Transactions. 2021. Vol. 50. No. 42. pp. 14994-14999.
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RIS
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TY - JOUR
DO - 10.1039/D1DT02823E
UR - https://xlink.rsc.org/?DOI=D1DT02823E
TI - Deprotonated diaminocarbene platinum complexes for thermoresponsive luminescent silicone materials: both catalysts and luminophores.
T2 - Dalton Transactions
AU - Dobrynin, Andrey V
AU - Kasatkina, Svetlana O
AU - Baykov, Sergey V
AU - Savko, Polina Y
AU - Antonov, N S
AU - Mikherdov, Alexander
AU - Boyarskiy, Vadim P
AU - Islamova, Regina M
PY - 2021
DA - 2021/10/11
PB - Royal Society of Chemistry (RSC)
SP - 14994-14999
IS - 42
VL - 50
PMID - 34693947
SN - 1477-9226
SN - 1477-9234
ER -
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BibTex (до 50 авторов)
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@article{2021_Dobrynin,
author = {Andrey V Dobrynin and Svetlana O Kasatkina and Sergey V Baykov and Polina Y Savko and N S Antonov and Alexander Mikherdov and Vadim P Boyarskiy and Regina M Islamova},
title = {Deprotonated diaminocarbene platinum complexes for thermoresponsive luminescent silicone materials: both catalysts and luminophores.},
journal = {Dalton Transactions},
year = {2021},
volume = {50},
publisher = {Royal Society of Chemistry (RSC)},
month = {oct},
url = {https://xlink.rsc.org/?DOI=D1DT02823E},
number = {42},
pages = {14994--14999},
doi = {10.1039/D1DT02823E}
}
Цитировать
MLA
Скопировать
Dobrynin, Andrey V., et al. “Deprotonated diaminocarbene platinum complexes for thermoresponsive luminescent silicone materials: both catalysts and luminophores..” Dalton Transactions, vol. 50, no. 42, Oct. 2021, pp. 14994-14999. https://xlink.rsc.org/?DOI=D1DT02823E.