Electropolymerization of D–A–D type monomers consisting of triphenylamine and substituted quinoxaline moieties for electrochromic devices
Тип публикации: Journal Article
Дата публикации: 2021-09-14
scimago Q2
wos Q3
БС1
SJR: 0.493
CiteScore: 5.0
Impact factor: 2.5
ISSN: 11440546, 13699261
Materials Chemistry
General Chemistry
Catalysis
Краткое описание
Three novel donor–accepter–donor (D–A–D) type monomers (TPAQ-Ph, TPAQ-PhOMe and TPAQ-Phen) consisting of triphenylamine (TPA) and substituted quinoxaline moieties were synthesized, and further electropolymerized for electrochromic devices. Polymers PTPAQ-Ph and PTPAQ-PhOMe with two twisted substituents on the π-conjugated backbone exhibited efficient electrochromic properties, involving high optical contrast up to 70%, short response time less than 3 s, high color coloration efficiency over 200 cm2 C−1, and good cycle stability. However, polymer PTPAQ-Phen employing a fused electron acceptor unit with high coplanarity showed poor electrochromic performance and low stability. Moreover, electrochromic devices based on these three polymers were fabricated and characterized. The result demonstrates that the molecular configuration of the designed monomer is crucial for electrochromic performance.
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Fu W. et al. Electropolymerization of D–A–D type monomers consisting of triphenylamine and substituted quinoxaline moieties for electrochromic devices // New Journal of Chemistry. 2021. Vol. 45. No. 40. pp. 19082-19087.
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Fu W., Chen H., Han Y., WANG W., Zhang R., Liu J. Electropolymerization of D–A–D type monomers consisting of triphenylamine and substituted quinoxaline moieties for electrochromic devices // New Journal of Chemistry. 2021. Vol. 45. No. 40. pp. 19082-19087.
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TY - JOUR
DO - 10.1039/d1nj04074j
UR - https://xlink.rsc.org/?DOI=D1NJ04074J
TI - Electropolymerization of D–A–D type monomers consisting of triphenylamine and substituted quinoxaline moieties for electrochromic devices
T2 - New Journal of Chemistry
AU - Fu, Wenan
AU - Chen, Hongjin
AU - Han, Yiying
AU - WANG, WENYUAN
AU - Zhang, Rui
AU - Liu, Jian
PY - 2021
DA - 2021/09/14
PB - Royal Society of Chemistry (RSC)
SP - 19082-19087
IS - 40
VL - 45
SN - 1144-0546
SN - 1369-9261
ER -
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@article{2021_Fu,
author = {Wenan Fu and Hongjin Chen and Yiying Han and WENYUAN WANG and Rui Zhang and Jian Liu},
title = {Electropolymerization of D–A–D type monomers consisting of triphenylamine and substituted quinoxaline moieties for electrochromic devices},
journal = {New Journal of Chemistry},
year = {2021},
volume = {45},
publisher = {Royal Society of Chemistry (RSC)},
month = {sep},
url = {https://xlink.rsc.org/?DOI=D1NJ04074J},
number = {40},
pages = {19082--19087},
doi = {10.1039/d1nj04074j}
}
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MLA
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Fu, Wenan, et al. “Electropolymerization of D–A–D type monomers consisting of triphenylamine and substituted quinoxaline moieties for electrochromic devices.” New Journal of Chemistry, vol. 45, no. 40, Sep. 2021, pp. 19082-19087. https://xlink.rsc.org/?DOI=D1NJ04074J.