Open Access
Highly efficient Ru(ii )–alkylidene based Hoveyda–Grubbs catalysts for ring-closing metathesis reactions
Publication type: Journal Article
Publication date: 2021-11-24
scimago Q1
wos Q2
SJR: 0.777
CiteScore: 7.6
Impact factor: 4.6
ISSN: 20462069
PubMed ID:
35498076
General Chemistry
General Chemical Engineering
Abstract
Three novel phosphine-free Ru-alkylidenes (7a-7c) have been synthesized and utilized as efficient catalysts for ring closing metathesis (RCM) reaction. Spectroscopic data, i.e. NMR and HRMS, along with single crystal X-ray diffraction analysis, were used to confirm their chemical structures. The tosylated carbenoid 7b showed the highest efficiency in cyclizing different acyclic diene substrates. RCM of various (un)substituted N,N-diallylaniline derivatives and stereoselective RCM of different macromolecular dienes were well tolerated using only a catalytic amount (0.5-2.0 mol%) of the additive catalyst (7b) as compared to the well-known Grubbs (II) and Hoveyda-Grubbs (II) catalysts.
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9
Total citations:
9
Citations from 2024:
7
(77.77%)
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GOST
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Al Enezi M. Y. et al. Highly efficient Ru(ii)–alkylidene based Hoveyda–Grubbs catalysts for ring-closing metathesis reactions // RSC Advances. 2021. Vol. 11. No. 60. pp. 37866-37876.
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Al Enezi M. Y., Al-Enezi M. Y., JOHN E., Ibrahim Y. A., Al Awadi N. A. Highly efficient Ru(ii)–alkylidene based Hoveyda–Grubbs catalysts for ring-closing metathesis reactions // RSC Advances. 2021. Vol. 11. No. 60. pp. 37866-37876.
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RIS
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TY - JOUR
DO - 10.1039/d1ra07428h
UR - https://xlink.rsc.org/?DOI=D1RA07428H
TI - Highly efficient Ru(ii)–alkylidene based Hoveyda–Grubbs catalysts for ring-closing metathesis reactions
T2 - RSC Advances
AU - Al Enezi, Mariam Y
AU - Al-Enezi, Mariam Y.
AU - JOHN, ELIZABETH
AU - Ibrahim, Yehia A
AU - Al Awadi, Nouria A
PY - 2021
DA - 2021/11/24
PB - Royal Society of Chemistry (RSC)
SP - 37866-37876
IS - 60
VL - 11
PMID - 35498076
SN - 2046-2069
ER -
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BibTex (up to 50 authors)
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@article{2021_Al Enezi,
author = {Mariam Y Al Enezi and Mariam Y. Al-Enezi and ELIZABETH JOHN and Yehia A Ibrahim and Nouria A Al Awadi},
title = {Highly efficient Ru(ii)–alkylidene based Hoveyda–Grubbs catalysts for ring-closing metathesis reactions},
journal = {RSC Advances},
year = {2021},
volume = {11},
publisher = {Royal Society of Chemistry (RSC)},
month = {nov},
url = {https://xlink.rsc.org/?DOI=D1RA07428H},
number = {60},
pages = {37866--37876},
doi = {10.1039/d1ra07428h}
}
Cite this
MLA
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Al Enezi, Mariam Y., et al. “Highly efficient Ru(ii)–alkylidene based Hoveyda–Grubbs catalysts for ring-closing metathesis reactions.” RSC Advances, vol. 11, no. 60, Nov. 2021, pp. 37866-37876. https://xlink.rsc.org/?DOI=D1RA07428H.