Chemical Communications, volume 58, issue 17, pages 2874-2877
Unraveling the reactivity of the azo bridge in 3,3′-(5-dinitromethyl-1,2,4-oxadiazolyl)-4,4′-azofurazanate in the synthesis of energetic compounds
Peng Chen
1, 2
,
Lili Qiu
1, 2
,
Ping Yin
1, 2
,
Chunlin He
1, 2, 3, 4
,
Siping Pang
2
,
Jean'ne M. Shreeve
3, 4
2
3
Department of Chemistry, University of Idaho, Moscow, Idaho, 83844-2343, USA
|
4
Department of Chemistry, University of Idaho, Moscow, Idaho, USA
|
Publication type: Journal Article
Publication date: 2022-02-01
Journal:
Chemical Communications
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 4.9
ISSN: 13597345, 1364548X
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Abstract
The introduction of an azo bridge into an energetic compound is an efficient strategy to improve its nitrogen content, heat of formation and detonation performances. 3,3'-(5-Methyl dinitroacetate-1,2,4-oxadiazolyl)-4,4'-azofurazan exhibits unusual reactivity with several bases while preparing its corresponding azo bridged energetic salts. These interesting phenomena were explained by both experimental and theoretical calculations with Gaussian 09. The physical and chemical properties of three energetic salts were evaluated. These materials exhibit high densities, excellent detonation properties and acceptable sensitivities.
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Citations by publishers
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3
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5
6
7
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Elsevier
7 publications, 36.84%
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4 publications, 21.05%
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2 publications, 10.53%
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1 publication, 5.26%
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1
2
3
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Chen P. et al. Unraveling the reactivity of the azo bridge in 3,3′-(5-dinitromethyl-1,2,4-oxadiazolyl)-4,4′-azofurazanate in the synthesis of energetic compounds // Chemical Communications. 2022. Vol. 58. No. 17. pp. 2874-2877.
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Chen P., Qiu L., Yin P., He C., Pang S., Shreeve J. M. Unraveling the reactivity of the azo bridge in 3,3′-(5-dinitromethyl-1,2,4-oxadiazolyl)-4,4′-azofurazanate in the synthesis of energetic compounds // Chemical Communications. 2022. Vol. 58. No. 17. pp. 2874-2877.
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TY - JOUR
DO - 10.1039/d2cc00215a
UR - https://doi.org/10.1039/d2cc00215a
TI - Unraveling the reactivity of the azo bridge in 3,3′-(5-dinitromethyl-1,2,4-oxadiazolyl)-4,4′-azofurazanate in the synthesis of energetic compounds
T2 - Chemical Communications
AU - Chen, Peng
AU - Qiu, Lili
AU - Yin, Ping
AU - He, Chunlin
AU - Pang, Siping
AU - Shreeve, Jean'ne M.
PY - 2022
DA - 2022/02/01 00:00:00
PB - Royal Society of Chemistry (RSC)
SP - 2874-2877
IS - 17
VL - 58
SN - 1359-7345
SN - 1364-548X
ER -
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@article{2022_Chen,
author = {Peng Chen and Lili Qiu and Ping Yin and Chunlin He and Siping Pang and Jean'ne M. Shreeve},
title = {Unraveling the reactivity of the azo bridge in 3,3′-(5-dinitromethyl-1,2,4-oxadiazolyl)-4,4′-azofurazanate in the synthesis of energetic compounds},
journal = {Chemical Communications},
year = {2022},
volume = {58},
publisher = {Royal Society of Chemistry (RSC)},
month = {feb},
url = {https://doi.org/10.1039/d2cc00215a},
number = {17},
pages = {2874--2877},
doi = {10.1039/d2cc00215a}
}
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Chen, Peng, et al. “Unraveling the reactivity of the azo bridge in 3,3′-(5-dinitromethyl-1,2,4-oxadiazolyl)-4,4′-azofurazanate in the synthesis of energetic compounds.” Chemical Communications, vol. 58, no. 17, Feb. 2022, pp. 2874-2877. https://doi.org/10.1039/d2cc00215a.
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