Physical Chemistry Chemical Physics, volume 24, issue 13, pages 7882-7892
Self-association of diphenylpnictoginic acids in solution and solid state: covalent vs. hydrogen bonding.
Publication type: Journal Article
Publication date: 2022-03-15
Journal:
Physical Chemistry Chemical Physics
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 3.3
ISSN: 14639076, 14639084
Physical and Theoretical Chemistry
General Physics and Astronomy
Abstract
Triphenylpnictogens were oxidized to access diphenylpnictioginic acids Ph2XOOH (X = P, As, Sb, Bi). It was shown that oxidation with chloramine-T does not lead to the cleavage of a C-pnictogen bond. The preliminary reductive cleavage with sodium in liquid ammonia followed by the oxidation with hydrogen peroxide was successfully utilised for the synthesis of diphenylphosphinic and diphenylarsinic acids. It was shown that in solid state (by means of XRD), all diphenylpnictoginic acids form polymeric chains. Diphenylbismuthinic and diphenylantimonic acids form polymeric covalent adducts, while diphenylphosphinic and diphenylarsinic chains are associated through hydrogen bonding. Unlike diphenylphosphinic acid, diphenilarsinic acid forms two polymorphs of hydrogen-bonded infinite chains. In solution in a polar aprotic solvent diphenylarsinic acid, similarly to dimethylarsinic, forms hydrogen-bonded cyclic dimers together with a small amount of cyclic trimers.
Citations by journals
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1
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Organic and Biomolecular Chemistry
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Organic and Biomolecular Chemistry
1 publication, 33.33%
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Physical Chemistry Chemical Physics
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1 publication, 33.33%
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ChemPlusChem
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ChemPlusChem
1 publication, 33.33%
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Citations by publishers
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1
2
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
2 publications, 66.67%
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Wiley
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Wiley
1 publication, 33.33%
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1
2
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Yakubenko A. A. et al. Self-association of diphenylpnictoginic acids in solution and solid state: covalent vs. hydrogen bonding. // Physical Chemistry Chemical Physics. 2022. Vol. 24. No. 13. pp. 7882-7892.
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Yakubenko A. A., Puzyk A. M., Korostelev V. O., Mulloyarova V. V., Tupikina E. Yu., Tolstoy P. M., Antonov A. S. Self-association of diphenylpnictoginic acids in solution and solid state: covalent vs. hydrogen bonding. // Physical Chemistry Chemical Physics. 2022. Vol. 24. No. 13. pp. 7882-7892.
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TY - JOUR
DO - 10.1039/D2CP00286H
UR - https://doi.org/10.1039%2FD2CP00286H
TI - Self-association of diphenylpnictoginic acids in solution and solid state: covalent vs. hydrogen bonding.
T2 - Physical Chemistry Chemical Physics
AU - Yakubenko, Artyom A
AU - Puzyk, Aleksandra M
AU - Korostelev, Vladislav O
AU - Mulloyarova, Valeriia V
AU - Tupikina, E Yu
AU - Tolstoy, Peter M.
AU - Antonov, Alexander S.
PY - 2022
DA - 2022/03/15 00:00:00
PB - Royal Society of Chemistry (RSC)
SP - 7882-7892
IS - 13
VL - 24
SN - 1463-9076
SN - 1463-9084
ER -
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@article{2022_Yakubenko,
author = {Artyom A Yakubenko and Aleksandra M Puzyk and Vladislav O Korostelev and Valeriia V Mulloyarova and E Yu Tupikina and Peter M. Tolstoy and Alexander S. Antonov},
title = {Self-association of diphenylpnictoginic acids in solution and solid state: covalent vs. hydrogen bonding.},
journal = {Physical Chemistry Chemical Physics},
year = {2022},
volume = {24},
publisher = {Royal Society of Chemistry (RSC)},
month = {mar},
url = {https://doi.org/10.1039%2FD2CP00286H},
number = {13},
pages = {7882--7892},
doi = {10.1039/D2CP00286H}
}
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MLA
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Yakubenko, Artyom A., et al. “Self-association of diphenylpnictoginic acids in solution and solid state: covalent vs. hydrogen bonding..” Physical Chemistry Chemical Physics, vol. 24, no. 13, Mar. 2022, pp. 7882-7892. https://doi.org/10.1039%2FD2CP00286H.