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Substitution pattern in ruthenium octa-n-butoxyphthalocyanine complexes influence their reactivity in N-H carbene insertions
Тип публикации: Journal Article
Дата публикации: 2023-01-01
scimago Q2
wos Q2
БС1
SJR: 0.600
CiteScore: 5.2
Impact factor: 2.7
ISSN: 14770520, 14770539
PubMed ID:
36448301
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Краткое описание
Ruthenium phthalocyanine complexes bearing n-OBu substituents in the peripheral or non-peripheral positions are efficient catalysts for the selective double or single carbene insertion to the amine N-H bonds. This complementary reactivity of two Ru complexes can be used for the synthesis of asymmetric tertiary amines and diamines bearing different substituents and has been demonstrated by two examples of readily available primary amines using different carbene precursors in successive reactions.
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Kroitor A. P. et al. Substitution pattern in ruthenium octa-n-butoxyphthalocyanine complexes influence their reactivity in N-H carbene insertions // Organic and Biomolecular Chemistry. 2023. Vol. 21. No. 1. pp. 69-74.
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Kroitor A. P., Dmitrienko A. A., Martynov A. G., Gorbunova Y. G., Sorokin A. B. Substitution pattern in ruthenium octa-n-butoxyphthalocyanine complexes influence their reactivity in N-H carbene insertions // Organic and Biomolecular Chemistry. 2023. Vol. 21. No. 1. pp. 69-74.
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TY - JOUR
DO - 10.1039/d2ob01861f
UR - https://xlink.rsc.org/?DOI=D2OB01861F
TI - Substitution pattern in ruthenium octa-n-butoxyphthalocyanine complexes influence their reactivity in N-H carbene insertions
T2 - Organic and Biomolecular Chemistry
AU - Kroitor, Andrey P
AU - Dmitrienko, Alexander A
AU - Martynov, Alexander G.
AU - Gorbunova, Yulia G.
AU - Sorokin, Alexander B
PY - 2023
DA - 2023/01/01
PB - Royal Society of Chemistry (RSC)
SP - 69-74
IS - 1
VL - 21
PMID - 36448301
SN - 1477-0520
SN - 1477-0539
ER -
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@article{2023_Kroitor,
author = {Andrey P Kroitor and Alexander A Dmitrienko and Alexander G. Martynov and Yulia G. Gorbunova and Alexander B Sorokin},
title = {Substitution pattern in ruthenium octa-n-butoxyphthalocyanine complexes influence their reactivity in N-H carbene insertions},
journal = {Organic and Biomolecular Chemistry},
year = {2023},
volume = {21},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://xlink.rsc.org/?DOI=D2OB01861F},
number = {1},
pages = {69--74},
doi = {10.1039/d2ob01861f}
}
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MLA
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Kroitor, Andrey P., et al. “Substitution pattern in ruthenium octa-n-butoxyphthalocyanine complexes influence their reactivity in N-H carbene insertions.” Organic and Biomolecular Chemistry, vol. 21, no. 1, Jan. 2023, pp. 69-74. https://xlink.rsc.org/?DOI=D2OB01861F.